[(CH3)3NCH2CH2NH3] SNl4: A layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts

Zhengtao Xu; David B. Mitzi; David R. Medeiros

doi:10.1021/ic0261981

[(CH₃)₃NCH₂CH₂NH₃] SNl₄: A layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts

Zhengtao Xu, David B. Mitzi, David R. Medeiros

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

69 Citations (Scopus)

Abstract

The organic-inorganic hybrid [(CH₃)₃NCH₂CH₂NH₃] Snl₄ presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 Å are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other Snl₄^2--based layered perovskite structures.

Original language	English
Pages (from-to)	1400-1402
Journal	Inorganic Chemistry
Volume	42
Issue number	5
DOIs	https://doi.org/10.1021/ic0261981
Publication status	Published - 10 Mar 2003
Externally published	Yes

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@article{2209777121e8477699279c9d29f520b0,

title = "[(CH3)3NCH2CH2NH3] SNl4: A layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts",

abstract = "The organic-inorganic hybrid [(CH3)3NCH2CH2NH3] Snl4 presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 {\AA} are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other Snl42--based layered perovskite structures.",

author = "Zhengtao Xu and Mitzi, {David B.} and Medeiros, {David R.}",

year = "2003",

month = mar,

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doi = "10.1021/ic0261981",

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volume = "42",

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journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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T1 - [(CH3)3NCH2CH2NH3] SNl4

T2 - A layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts

AU - Xu, Zhengtao

AU - Mitzi, David B.

AU - Medeiros, David R.

PY - 2003/3/10

Y1 - 2003/3/10

N2 - The organic-inorganic hybrid [(CH3)3NCH2CH2NH3] Snl4 presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 Å are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other Snl42--based layered perovskite structures.

AB - The organic-inorganic hybrid [(CH3)3NCH2CH2NH3] Snl4 presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 Å are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other Snl42--based layered perovskite structures.

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U2 - 10.1021/ic0261981

DO - 10.1021/ic0261981

M3 - RGC 21 - Publication in refereed journal

SN - 0020-1669

VL - 42

SP - 1400

EP - 1402

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -