Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction

Hoi-Lun Kwong; Kwok-Mei Lau; Wing-Sze Lee; Wing-Tak Wong

doi:10.1039/a902177i

Author(s)

Hoi-Lun Kwong
Kwok-Mei Lau
Wing-Sze Lee
Wing-Tak Wong

Detail(s)

Original language	English
Pages (from-to)	629-632
Journal / Publication	New Journal of Chemistry
Volume	23
Issue number	6
Publication status	Published - 1999

Link(s)

DOI	DOI https://doi.org/10.1039/a902177i Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0032813641&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(4d23bca3-a8a6-4cc4-8046-e9adeba1a696).html

Abstract

A chiral bipyridine zinc(II) complex, Zn(L)Cl₂ (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl₂ with AgCF₃SO₃ gave Zn(L)(CF₃SO₃)₂ in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%.

Citation Format(s)

[ RIS ] [ BibTeX ]

Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction. / Kwong, Hoi-Lun; Lau, Kwok-Mei; Lee, Wing-Sze et al.
In: New Journal of Chemistry, Vol. 23, No. 6, 1999, p. 629-632.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Kwong, H-L, Lau, K-M, Lee, W-S & Wong, W-T 1999, 'Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction', New Journal of Chemistry, vol. 23, no. 6, pp. 629-632. https://doi.org/10.1039/a902177i

Kwong, H.-L., Lau, K.-M., Lee, W.-S., & Wong, W.-T. (1999). Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction. New Journal of Chemistry, 23(6), 629-632. https://doi.org/10.1039/a902177i

Kwong HL, Lau KM, Lee WS, Wong WT. Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction. New Journal of Chemistry. 1999;23(6):629-632. doi: 10.1039/a902177i

Kwong, Hoi-Lun ; Lau, Kwok-Mei ; Lee, Wing-Sze et al. / Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction. In: New Journal of Chemistry. 1999 ; Vol. 23, No. 6. pp. 629-632.