TY - JOUR
T1 - Chemistry of Heterometallic Phenyl Imido and Phosphinidene Clusters
AU - Chi, Yun
AU - Lin, Ren-Chiun
AU - Peng, Shie-Ming
AU - Lee, Gene-Hsiang
PY - 1992/9
Y1 - 1992/9
N2 - Triruthenium imido cluster Ru3(CO)10(μ3-NPh)(1) reacts with tungsten hydride LW(CO)3H to afford heterometallic imido clusters LWRu2(CO)8(μ-H) (μ3-NPh), L=Cp, (IIa); L=Cp*, (IIb), whereas the respective phosphinidene complexes LWRu2(CO)8(μ-H)(μ3-PPh), L=Cp, (IXa); L=Cp*, (IXb), were generated via reaction of Ru3(CO)10(μ-H)(μ-PPh2) with CpW(CO)3H and with CP*W(CO)3H followed by thermolysis in the presence of carbon monoxide. Their molecular structure, solution dynamics, and the subsequent reaction with hexafluoro-2-butyne are presented.
AB - Triruthenium imido cluster Ru3(CO)10(μ3-NPh)(1) reacts with tungsten hydride LW(CO)3H to afford heterometallic imido clusters LWRu2(CO)8(μ-H) (μ3-NPh), L=Cp, (IIa); L=Cp*, (IIb), whereas the respective phosphinidene complexes LWRu2(CO)8(μ-H)(μ3-PPh), L=Cp, (IXa); L=Cp*, (IXb), were generated via reaction of Ru3(CO)10(μ-H)(μ-PPh2) with CpW(CO)3H and with CP*W(CO)3H followed by thermolysis in the presence of carbon monoxide. Their molecular structure, solution dynamics, and the subsequent reaction with hexafluoro-2-butyne are presented.
KW - Heterometallic cluster
KW - imido
KW - phosphinidene
KW - ruthenium
KW - tungsten
UR - http://www.scopus.com/inward/record.url?scp=0010777482&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0010777482&origin=recordpage
U2 - 10.1007/BF01028550
DO - 10.1007/BF01028550
M3 - RGC 21 - Publication in refereed journal
SN - 1040-7278
VL - 3
SP - 333
EP - 345
JO - Journal of Cluster Science
JF - Journal of Cluster Science
IS - 3
ER -