Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries

Tianyi Song; Chenchen Wang; Pinit Kidkhunthod; Xiaolong Zhou; Anquan Zhu; Yuanqi Lan; Kunlun Liu; Jianli Liang; Wenjun Zhang; Wenjiao Yao; Yongbing Tang; Chun-Sing Lee

doi:10.1016/j.ensm.2025.104106

Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries

Tianyi Song, Chenchen Wang, Pinit Kidkhunthod, Xiaolong Zhou, Anquan Zhu, Yuanqi Lan, Kunlun Liu, Jianli Liang, Wenjun Zhang, Wenjiao Yao^*, Yongbing Tang^*, Chun-Sing Lee^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Abstract

O3-type Mn-Fe-Ni layer oxide cathodes show great commercialization potential due to their high capacities and simple synthesis. Nevertheless, simultaneously achieving high energy density and good cycling stability remains challenging. Herein, we introduce a chemical disordering strategy to create O3-Na_0.83Mn_0.35Fe_0.15Ni_0.15Cu_0.10Co_0.20Sn_0.05O₂ (MFNCCS) cathode. The chemical disordering strategy was implemented through selective multi-transition metal substitution and quenching during synthesis. The former promotes a high entropy effect, while the latter is beneficial to increasing the quenching disorder degree, functioning a synergy effect in suppressing irreversible multi-phase transitions and promoting cycling stability. As a result, the MFNCCS cathode can retain 91.6 % (∼103.3 mAh g^–¹) of its capacity after 500 cycles at 200 mA g^–¹, with an energy density of 285.3 Wh kg⁻¹ at the 500^th cycle, which is superior to previously reported state-of-the-art layered oxide cathodes in the voltage range of 2.0–4.3 V. Besides, it achieves stable cycling within 2.0–4.3 V over temperature range of –20 to 25 °C. This work offers new insights for high-voltage stable layered cathodes in wide-temperature SIBs. © 2025 Elsevier B.V.

Original language	English
Article number	104106
Journal	Energy Storage Materials
Volume	76
Online published	21 Feb 2025
DOIs	https://doi.org/10.1016/j.ensm.2025.104106
Publication status	Published - Mar 2025

Funding

This work was supported by the Research Grant Council [RGC Reference: N_CityU104/20]; Shenzhen Science and Technology Innovation Program [Grant No. SGDX20230116092055008]; National Natural Science Foundation of China [Grant No. 52372250, 52061160484, 52125105]; National Research Council of Thailand [NRCT, grant No. N42A650253]; the NSRF via the Program Management Unit for Human Resources & Institutional Development, Research and Innovation [Grant No. B50G670108]; Shenzhen Science and Technology Planning Project [Grant No. KJZD20230923113859006, RCYX20221008092850072]; Guangdong Basic and Applied Basic Research Foundation [Grant No. 2024A1515030076, 2024A1515011670].

Research Keywords

Chemical disordering
High-voltage stability
Sodium-ion batteries
Transition metal oxide cathode
−20–25 °C

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ensm.2025.104106

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@article{84cfd72f06d24267951a243c12188f9f,

title = "Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries",

abstract = "O3-type Mn-Fe-Ni layer oxide cathodes show great commercialization potential due to their high capacities and simple synthesis. Nevertheless, simultaneously achieving high energy density and good cycling stability remains challenging. Herein, we introduce a chemical disordering strategy to create O3-Na0.83Mn0.35Fe0.15Ni0.15Cu0.10Co0.20Sn0.05O2 (MFNCCS) cathode. The chemical disordering strategy was implemented through selective multi-transition metal substitution and quenching during synthesis. The former promotes a high entropy effect, while the latter is beneficial to increasing the quenching disorder degree, functioning a synergy effect in suppressing irreversible multi-phase transitions and promoting cycling stability. As a result, the MFNCCS cathode can retain 91.6 % (∼103.3 mAh g–1) of its capacity after 500 cycles at 200 mA g–1, with an energy density of 285.3 Wh kg⁻1 at the 500th cycle, which is superior to previously reported state-of-the-art layered oxide cathodes in the voltage range of 2.0–4.3 V. Besides, it achieves stable cycling within 2.0–4.3 V over temperature range of –20 to 25 °C. This work offers new insights for high-voltage stable layered cathodes in wide-temperature SIBs. {\textcopyright} 2025 Elsevier B.V.",

keywords = "Chemical disordering, High-voltage stability, Sodium-ion batteries, Transition metal oxide cathode, −20–25 °C",

author = "Tianyi Song and Chenchen Wang and Pinit Kidkhunthod and Xiaolong Zhou and Anquan Zhu and Yuanqi Lan and Kunlun Liu and Jianli Liang and Wenjun Zhang and Wenjiao Yao and Yongbing Tang and Chun-Sing Lee",

year = "2025",

month = mar,

doi = "10.1016/j.ensm.2025.104106",

language = "English",

volume = "76",

journal = "Energy Storage Materials",

issn = "2405-8297",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries

AU - Song, Tianyi

AU - Wang, Chenchen

AU - Kidkhunthod, Pinit

AU - Zhou, Xiaolong

AU - Zhu, Anquan

AU - Lan, Yuanqi

AU - Liu, Kunlun

AU - Liang, Jianli

AU - Zhang, Wenjun

AU - Yao, Wenjiao

AU - Tang, Yongbing

AU - Lee, Chun-Sing

PY - 2025/3

Y1 - 2025/3

N2 - O3-type Mn-Fe-Ni layer oxide cathodes show great commercialization potential due to their high capacities and simple synthesis. Nevertheless, simultaneously achieving high energy density and good cycling stability remains challenging. Herein, we introduce a chemical disordering strategy to create O3-Na0.83Mn0.35Fe0.15Ni0.15Cu0.10Co0.20Sn0.05O2 (MFNCCS) cathode. The chemical disordering strategy was implemented through selective multi-transition metal substitution and quenching during synthesis. The former promotes a high entropy effect, while the latter is beneficial to increasing the quenching disorder degree, functioning a synergy effect in suppressing irreversible multi-phase transitions and promoting cycling stability. As a result, the MFNCCS cathode can retain 91.6 % (∼103.3 mAh g–1) of its capacity after 500 cycles at 200 mA g–1, with an energy density of 285.3 Wh kg⁻1 at the 500th cycle, which is superior to previously reported state-of-the-art layered oxide cathodes in the voltage range of 2.0–4.3 V. Besides, it achieves stable cycling within 2.0–4.3 V over temperature range of –20 to 25 °C. This work offers new insights for high-voltage stable layered cathodes in wide-temperature SIBs. © 2025 Elsevier B.V.

AB - O3-type Mn-Fe-Ni layer oxide cathodes show great commercialization potential due to their high capacities and simple synthesis. Nevertheless, simultaneously achieving high energy density and good cycling stability remains challenging. Herein, we introduce a chemical disordering strategy to create O3-Na0.83Mn0.35Fe0.15Ni0.15Cu0.10Co0.20Sn0.05O2 (MFNCCS) cathode. The chemical disordering strategy was implemented through selective multi-transition metal substitution and quenching during synthesis. The former promotes a high entropy effect, while the latter is beneficial to increasing the quenching disorder degree, functioning a synergy effect in suppressing irreversible multi-phase transitions and promoting cycling stability. As a result, the MFNCCS cathode can retain 91.6 % (∼103.3 mAh g–1) of its capacity after 500 cycles at 200 mA g–1, with an energy density of 285.3 Wh kg⁻1 at the 500th cycle, which is superior to previously reported state-of-the-art layered oxide cathodes in the voltage range of 2.0–4.3 V. Besides, it achieves stable cycling within 2.0–4.3 V over temperature range of –20 to 25 °C. This work offers new insights for high-voltage stable layered cathodes in wide-temperature SIBs. © 2025 Elsevier B.V.

KW - Chemical disordering

KW - High-voltage stability

KW - Sodium-ion batteries

KW - Transition metal oxide cathode

KW - −20–25 °C

UR - http://www.scopus.com/inward/record.url?scp=85217932226&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85217932226&origin=recordpage

U2 - 10.1016/j.ensm.2025.104106

DO - 10.1016/j.ensm.2025.104106

M3 - RGC 21 - Publication in refereed journal

SN - 2405-8297

VL - 76

JO - Energy Storage Materials

JF - Energy Storage Materials

M1 - 104106

ER -

Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries

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NSFC: Design and Mechanism Investigation of High-voltage Solid-state Non-lithium Alkali Metal-ion Batteries

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Chemical disorder engineering enables high-voltage stable oxide cathodes over –20–25 ℃ in sodium-ion batteries

Abstract

Funding

Research Keywords

UN SDGs

Access Output

Other Access Options

Permanent Link

Other Files and Links

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NSFC: Design and Mechanism Investigation of High-voltage Solid-state Non-lithium Alkali Metal-ion Batteries

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