Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

Qichun Zhang; In Chung; Joon I. Jang; John B. Ketterson; Mercouri G. Kanatzidis

doi:10.1021/ja903881m

Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb₇S₈Br₂](AlCl₄)₃

Qichun Zhang
, In Chung
, Joon I. Jang
, John B. Ketterson
, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

234 Citations (Scopus)

Abstract

(Graph Presented) The new cation [Sb₇S₈Br₂]³⁺ has a double-cubane structure and forms as the [AlCl₄]^- salt from the ionic liquid EMIMBr-AlCl₃ (EMIM = 1-ethyl-3-methylimidazolium) at 165 °C. The compound is noncentrosymmetric with space group P2₁2₁2₁ and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions. © 2009 American Chemical Society.

Original language	English
Pages (from-to)	9896-9897
Journal	Journal of the American Chemical Society
Volume	131
Issue number	29
Online published	6 Jul 2009
DOIs	https://doi.org/10.1021/ja903881m
Publication status	Published - 29 Jul 2009
Externally published	Yes

Access Output

10.1021/ja903881m

Other Access Options

Check CityUHK Library

Permanent Link

Right click to copy link

Cite this

@article{711cd8af73944dceb4415575debc5087,

title = "Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3",

abstract = "(Graph Presented) The new cation [Sb7S8Br2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 °C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions. {\textcopyright} 2009 American Chemical Society.",

author = "Qichun Zhang and In Chung and Jang, \{Joon I.\} and Ketterson, \{John B.\} and Kanatzidis, \{Mercouri G.\}",

year = "2009",

month = jul,

day = "29",

doi = "10.1021/ja903881m",

language = "English",

volume = "131",

pages = "9896--9897",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "29",

}

Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb₇S₈Br₂](AlCl₄)₃. / Zhang, Qichun; Chung, In; Jang, Joon I. et al.
In: Journal of the American Chemical Society, Vol. 131, No. 29, 29.07.2009, p. 9896-9897.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Chalcogenide Chemistry in Ionic Liquids

T2 - Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

AU - Zhang, Qichun

AU - Chung, In

AU - Jang, Joon I.

AU - Ketterson, John B.

AU - Kanatzidis, Mercouri G.

PY - 2009/7/29

Y1 - 2009/7/29

N2 - (Graph Presented) The new cation [Sb7S8Br2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 °C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions. © 2009 American Chemical Society.

AB - (Graph Presented) The new cation [Sb7S8Br2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 °C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions. © 2009 American Chemical Society.

UR - https://www.scopus.com/pages/publications/67651218697

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-67651218697&origin=recordpage

U2 - 10.1021/ja903881m

DO - 10.1021/ja903881m

M3 - RGC 21 - Publication in refereed journal

SN - 0002-7863

VL - 131

SP - 9896

EP - 9897

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 29

ER -