CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes

Xiangya Xu; Benjamin Pooi; Hajime Hirao; Soon Hyeok Hong

doi:10.1002/anie.201309371

Author(s)

Xiangya Xu
Benjamin Pooi
Hajime Hirao
Soon Hyeok Hong

Detail(s)

Original language	English
Pages (from-to)	1283-1287
Journal / Publication	Angewandte Chemie - International Edition
Volume	53
Issue number	5
Publication status	Published - 27 Jan 2014
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.201309371 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-84893944953&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(5e9e756c-105a-46a2-b6d0-68b8af082c3b).html

Abstract

The role of CH-π and CF-π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH-π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF-π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1- pentafluorophenylimidazol-2-ylidene) palladium(II). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Research Area(s)

π interactions, Conformation analysis, Hydrogen bonds, Noncovalent interactions, Palladium

Citation Format(s)

[ RIS ] [ BibTeX ]

CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes. / Xu, Xiangya; Pooi, Benjamin; Hirao, Hajime et al.
In: Angewandte Chemie - International Edition, Vol. 53, No. 5, 27.01.2014, p. 1283-1287.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Xu, X, Pooi, B, Hirao, H & Hong, SH 2014, 'CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes', Angewandte Chemie - International Edition, vol. 53, no. 5, pp. 1283-1287. https://doi.org/10.1002/anie.201309371

Xu, X., Pooi, B., Hirao, H., & Hong, S. H. (2014). CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes. Angewandte Chemie - International Edition, 53(5), 1283-1287. https://doi.org/10.1002/anie.201309371

Xu X, Pooi B, Hirao H, Hong SH. CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes. Angewandte Chemie - International Edition. 2014 Jan 27;53(5):1283-1287. doi: 10.1002/anie.201309371

Xu, Xiangya ; Pooi, Benjamin ; Hirao, Hajime et al. / CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes. In: Angewandte Chemie - International Edition. 2014 ; Vol. 53, No. 5. pp. 1283-1287.