TY - JOUR
T1 - Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand
AU - Tan, Peng
AU - Kwong, Hoi-Ki
AU - Lau, Tai-Chu
PY - 2015/8/7
Y1 - 2015/8/7
N2 - An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95% conversions and yields can be obtained.
AB - An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95% conversions and yields can be obtained.
UR - http://www.scopus.com/inward/record.url?scp=84937250184&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84937250184&origin=recordpage
U2 - 10.1039/c5cc02868j
DO - 10.1039/c5cc02868j
M3 - RGC 21 - Publication in refereed journal
SN - 0009-241X
VL - 51
SP - 12189
EP - 12192
JO - Chemical Communications
JF - Chemical Communications
IS - 61
ER -