Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand

Peng Tan; Hoi-Ki Kwong; Tai-Chu Lau

doi:10.1039/c5cc02868j

Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand

Peng Tan
, Hoi-Ki Kwong
, Tai-Chu Lau^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

52 Citations (Scopus)

Abstract

An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95% conversions and yields can be obtained.

Original language	English
Pages (from-to)	12189-12192
Journal	Chemical Communications
Volume	51
Issue number	61
Online published	16 Jun 2015
DOIs	https://doi.org/10.1039/c5cc02868j
Publication status	Published - 7 Aug 2015

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title = "Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand",

abstract = "An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95\% conversions and yields can be obtained.",

author = "Peng Tan and Hoi-Ki Kwong and Tai-Chu Lau",

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journal = "Chemical Communications",

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T1 - Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand

AU - Tan, Peng

AU - Kwong, Hoi-Ki

AU - Lau, Tai-Chu

PY - 2015/8/7

Y1 - 2015/8/7

N2 - An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95% conversions and yields can be obtained.

AB - An iron(III) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in catalytic alcohol oxidation >95% conversions and yields can be obtained.

UR - https://www.scopus.com/pages/publications/84937250184

UR - https://www.scopus.com/pages/publications/84937250184#tab=impact

U2 - 10.1039/c5cc02868j

DO - 10.1039/c5cc02868j

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 51

SP - 12189

EP - 12192

JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

Catalytic oxidation of water and alcohols by a robust iron(III) complex bearing a cross-bridged cyclam ligand

Abstract

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