Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes

Chi-Tung Yeung; Pang-Fei Teng; Ho-Lun Yeung; Wing-Tak Wong; Hoi-Lun Kwong

doi:10.1039/b712995e

Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes

Chi-Tung Yeung
, Pang-Fei Teng
, Ho-Lun Yeung
, Wing-Tak Wong
, Hoi-Lun Kwong

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

29 Citations (Scopus)

Abstract

Re(i) tricarbonyl bipyridine and terpyridine complexes catalyse stereospecific cyclopropanation of alkenes; high selectivity of cyclopropane vs coupling and an ee of 73% and 62% for cis- and trans-cyclopropanes of styrene respectively were achieved with the [Re(L)(CO)₃(MeCN)]OTf complex (L = chiral C₂-symmetric terpyridine ligand). © The Royal Society of Chemistry 2007.

Original language	English
Pages (from-to)	3859-3864
Journal	Organic and Biomolecular Chemistry
Volume	5
Issue number	23
DOIs	https://doi.org/10.1039/b712995e
Publication status	Published - 2007

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title = "Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes",

abstract = "Re(i) tricarbonyl bipyridine and terpyridine complexes catalyse stereospecific cyclopropanation of alkenes; high selectivity of cyclopropane vs coupling and an ee of 73\% and 62\% for cis- and trans-cyclopropanes of styrene respectively were achieved with the [Re(L)(CO)3(MeCN)]OTf complex (L = chiral C2-symmetric terpyridine ligand). {\textcopyright} The Royal Society of Chemistry 2007.",

author = "Chi-Tung Yeung and Pang-Fei Teng and Ho-Lun Yeung and Wing-Tak Wong and Hoi-Lun Kwong",

year = "2007",

doi = "10.1039/b712995e",

language = "English",

volume = "5",

pages = "3859--3864",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "23",

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TY - JOUR

T1 - Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes

AU - Yeung, Chi-Tung

AU - Teng, Pang-Fei

AU - Yeung, Ho-Lun

AU - Wong, Wing-Tak

AU - Kwong, Hoi-Lun

PY - 2007

Y1 - 2007

N2 - Re(i) tricarbonyl bipyridine and terpyridine complexes catalyse stereospecific cyclopropanation of alkenes; high selectivity of cyclopropane vs coupling and an ee of 73% and 62% for cis- and trans-cyclopropanes of styrene respectively were achieved with the [Re(L)(CO)3(MeCN)]OTf complex (L = chiral C2-symmetric terpyridine ligand). © The Royal Society of Chemistry 2007.

AB - Re(i) tricarbonyl bipyridine and terpyridine complexes catalyse stereospecific cyclopropanation of alkenes; high selectivity of cyclopropane vs coupling and an ee of 73% and 62% for cis- and trans-cyclopropanes of styrene respectively were achieved with the [Re(L)(CO)3(MeCN)]OTf complex (L = chiral C2-symmetric terpyridine ligand). © The Royal Society of Chemistry 2007.

UR - https://www.scopus.com/pages/publications/36148950511

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-36148950511&origin=recordpage

U2 - 10.1039/b712995e

DO - 10.1039/b712995e

M3 - RGC 21 - Publication in refereed journal

C2 - 18004467

SN - 1477-0520

VL - 5

SP - 3859

EP - 3864

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 23

ER -

Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes

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