Caro‐Cryptands : Tris‐carotenoid macrobicyclic ligands–synthesis, crystal structure, and dinuclear copper(I) complexes
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1069-1077 |
| Journal / Publication | Helvetica Chimica Acta |
| Volume | 75 |
| Issue number | 4 |
| Publication status | Published - 24 Jun 1992 |
| Externally published | Yes |
Link(s)
Abstract
The tris‐carotenoid macrobicycles 1 and 2 were obtained in good yields in a one‐step macrobicyclisation condensation between the tripode N(CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>)<sub>3</sub> and the polyolefinic dialdehydes 5 and 6. They form dinuclear cryptates by complexation of two Cu<sup>I</sup> ions. The crystal structure of the tris‐carotenoid compound 2 confirms that it contains three parallel polyolefinic strands. These substances may formally be considered as prototypes of molecular ‘cables’ formed by three electron‐conducting molecular wires. Copyright © 1992 Verlag GmbH & Co. KGaA, Weinheim
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Citation Format(s)
Caro‐Cryptands: Tris‐carotenoid macrobicyclic ligands–synthesis, crystal structure, and dinuclear copper(I) complexes. / Lehn, Jean‐Marie; Vigneron, Jean‐Pierre; Bkouche‐Waksman, Itka et al.
In: Helvetica Chimica Acta, Vol. 75, No. 4, 24.06.1992, p. 1069-1077.
In: Helvetica Chimica Acta, Vol. 75, No. 4, 24.06.1992, p. 1069-1077.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
