Carbonyl and Isocyanide Complexes of Rhenium

Chi-On Ng; Shun-Cheung Cheng; Chi-Chiu Ko

doi:10.1016/B978-0-12-820206-7.00043-3

Carbonyl and Isocyanide Complexes of Rhenium

Chi-On Ng, Shun-Cheung Cheng, Chi-Chiu Ko^*

^*Corresponding author for this work

Department of Chemistry

Research output: Chapters, Conference Papers, Creative and Literary Works › RGC 12 - Chapter in an edited book (Author) › peer-review

Abstract

Advanced molecular design of rhenium(I) complexes with application-specific properties has been a key driver in the development of new rhenium carbonyl and isocyano complexes. This article reviews the preparation, reactivity, and properties of rhenium carbonyl and isocyano complexes reported after 2005. New synthetic methodologies, including photochemical, mechanical, and microwave-assisted reactions, used to increase functionalization within these complexes are discussed. Moreover, selected popular topics, including photophysics, photocatalysis, photosensitization, and biomedical applications of these complexes, are also reviewed. © 2022 Elsevier Ltd. All rights reserved.

Original language	English
Title of host publication	Comprehensive Organometallic Chemistry IV
Editors	Gerard Parkin, Karsten Meyer, Dermot O'Hare, Scott R. Daly
Publisher	Elsevier
Chapter	6.07
Pages	553-622
Volume	6
Edition	4th
ISBN (Electronic)	9780323913508
ISBN (Print)	9780128202067
DOIs	https://doi.org/10.1016/B978-0-12-820206-7.00043-3
Publication status	Published - 2022

Research Keywords

Biological application
Carbene
Carbonyl
Decarbonylation
Diimine
Isocyanide
Luminescence
Phosphorescence
Photocatalyst
Photoligand substitution
Photoredox catalysis
Photosensitizer
Rhenium

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title = "Carbonyl and Isocyanide Complexes of Rhenium",

abstract = "Advanced molecular design of rhenium(I) complexes with application-specific properties has been a key driver in the development of new rhenium carbonyl and isocyano complexes. This article reviews the preparation, reactivity, and properties of rhenium carbonyl and isocyano complexes reported after 2005. New synthetic methodologies, including photochemical, mechanical, and microwave-assisted reactions, used to increase functionalization within these complexes are discussed. Moreover, selected popular topics, including photophysics, photocatalysis, photosensitization, and biomedical applications of these complexes, are also reviewed. {\textcopyright} 2022 Elsevier Ltd. All rights reserved.",

keywords = "Biological application, Carbene, Carbonyl, Decarbonylation, Diimine, Isocyanide, Luminescence, Phosphorescence, Photocatalyst, Photoligand substitution, Photoredox catalysis, Photosensitizer, Rhenium",

author = "Chi-On Ng and Shun-Cheung Cheng and Chi-Chiu Ko",

year = "2022",

doi = "10.1016/B978-0-12-820206-7.00043-3",

language = "English",

isbn = "9780128202067",

volume = "6",

pages = "553--622",

editor = "Gerard Parkin and Karsten Meyer and Dermot O'Hare and Daly, {Scott R.}",

booktitle = "Comprehensive Organometallic Chemistry IV",

publisher = "Elsevier",

edition = "4th",

}

Carbonyl and Isocyanide Complexes of Rhenium. / Ng, Chi-On; Cheng, Shun-Cheung; Ko, Chi-Chiu.
Comprehensive Organometallic Chemistry IV. ed. / Gerard Parkin; Karsten Meyer; Dermot O'Hare; Scott R. Daly. Vol. 6 4th. ed. Elsevier, 2022. p. 553-622.

Research output: Chapters, Conference Papers, Creative and Literary Works › RGC 12 - Chapter in an edited book (Author) › peer-review

TY - CHAP

T1 - Carbonyl and Isocyanide Complexes of Rhenium

AU - Ng, Chi-On

AU - Cheng, Shun-Cheung

AU - Ko, Chi-Chiu

PY - 2022

Y1 - 2022

N2 - Advanced molecular design of rhenium(I) complexes with application-specific properties has been a key driver in the development of new rhenium carbonyl and isocyano complexes. This article reviews the preparation, reactivity, and properties of rhenium carbonyl and isocyano complexes reported after 2005. New synthetic methodologies, including photochemical, mechanical, and microwave-assisted reactions, used to increase functionalization within these complexes are discussed. Moreover, selected popular topics, including photophysics, photocatalysis, photosensitization, and biomedical applications of these complexes, are also reviewed. © 2022 Elsevier Ltd. All rights reserved.

AB - Advanced molecular design of rhenium(I) complexes with application-specific properties has been a key driver in the development of new rhenium carbonyl and isocyano complexes. This article reviews the preparation, reactivity, and properties of rhenium carbonyl and isocyano complexes reported after 2005. New synthetic methodologies, including photochemical, mechanical, and microwave-assisted reactions, used to increase functionalization within these complexes are discussed. Moreover, selected popular topics, including photophysics, photocatalysis, photosensitization, and biomedical applications of these complexes, are also reviewed. © 2022 Elsevier Ltd. All rights reserved.

KW - Biological application

KW - Carbene

KW - Carbonyl

KW - Decarbonylation

KW - Diimine

KW - Isocyanide

KW - Luminescence

KW - Phosphorescence

KW - Photocatalyst

KW - Photoligand substitution

KW - Photoredox catalysis

KW - Photosensitizer

KW - Rhenium

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85175383301&origin=recordpage

U2 - 10.1016/B978-0-12-820206-7.00043-3

DO - 10.1016/B978-0-12-820206-7.00043-3

M3 - RGC 12 - Chapter in an edited book (Author)

SN - 9780128202067

VL - 6

SP - 553

EP - 622

BT - Comprehensive Organometallic Chemistry IV

A2 - Parkin, Gerard

A2 - Meyer, Karsten

A2 - O'Hare, Dermot

A2 - Daly, Scott R.

PB - Elsevier

ER -

Carbonyl and Isocyanide Complexes of Rhenium

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Research Keywords

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