Bright Monocompound Metal Halide Scintillator for Fast Neutron Radiography

Fast neutron imaging is a promising technique for visualizing objects containing dense, mixed light-and-heavy-elements materials, such as combustion engines, nuclear fuel assemblies, and fossils, where X-rays and thermal neutrons are ineffective. However, the limited efficiency of current detection technologies hinders their widespread adoption. Recoil proton detection using two-component scintillator screens composed of doped zinc sulfide (ZnS) microparticles in polypropylene (PP) remains the standard imaging tool due to the high light yield of ZnS. The efficiency is, however, restricted by the low volumetric fraction of ZnS, which cannot be increased without causing excessive light scattering and loss of resolution, while PP is still needed for substantial interaction with neutrons. In this work, a monocompound metal halide tetraphenylphosphonium manganese bromide (TPP₂MnBr₄) scintillator is explored as an alternative, exhibiting 1.5 times higher light output and fourfold higher light yield than conventional ZnS-based scintillators. This improvement arises from superior recoil proton energy utilization in the homogeneous structure of TPP₂MnBr₄ compared to the heterogeneous composition of PP/ZnS. Imaging tests show spatial resolution of around one line pair per millimeter, matching commercial PP/ZnS screens. These results indicate that TPP₂MnBr₄ scintillator can reduce exposure time and improve image quality, paving the way for efficient, high-resolution neutron imaging technologies. © 2025 The Author(s). Advanced Functional Materials published by Wiley-VCH GmbH.