BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor

J. M. Tobin; J. Liu; H. Hayes; M. Demleitner; D. Ellis; V. Arrighi; Z. Xu; F. Vilela

doi:10.1039/c6py01393g

BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor

J. M. Tobin, J. Liu, H. Hayes, M. Demleitner, D. Ellis, V. Arrighi, Z. Xu^*, F. Vilela^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

58 Citations (Scopus)

Abstract

BODIPY-based conjugated microporous polymers (BDP-CMP and PHTT-BDP) have been synthesised via two distinct methods of assembly: high-yielding Suzuki-Miyaura cross-coupling of BODIPY-containing building blocks, and post-synthetic conversion of an aldehyde-equipped CMP host that was synthesised in the absence of metal-based catalysts. Both approaches yielded BODIPY-based materials featuring a high BET surface area (484-769 m² g^-1) and a bathochromic shift in the maximum light absorbance (520-550 nm). Singlet oxygen production employing the BODIPY-based materials at 530 nm was carried out heterogeneously in a commercial photochemical flow reactor.

Original language	English
Pages (from-to)	6662-6670
Journal	Polymer Chemistry
Volume	7
Issue number	43
DOIs	https://doi.org/10.1039/c6py01393g
Publication status	Published - 21 Nov 2016

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title = "BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor",

abstract = "BODIPY-based conjugated microporous polymers (BDP-CMP and PHTT-BDP) have been synthesised via two distinct methods of assembly: high-yielding Suzuki-Miyaura cross-coupling of BODIPY-containing building blocks, and post-synthetic conversion of an aldehyde-equipped CMP host that was synthesised in the absence of metal-based catalysts. Both approaches yielded BODIPY-based materials featuring a high BET surface area (484-769 m2 g-1) and a bathochromic shift in the maximum light absorbance (520-550 nm). Singlet oxygen production employing the BODIPY-based materials at 530 nm was carried out heterogeneously in a commercial photochemical flow reactor.",

author = "Tobin, {J. M.} and J. Liu and H. Hayes and M. Demleitner and D. Ellis and V. Arrighi and Z. Xu and F. Vilela",

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language = "English",

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journal = "Polymer Chemistry",

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T1 - BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor

AU - Tobin, J. M.

AU - Liu, J.

AU - Hayes, H.

AU - Demleitner, M.

AU - Ellis, D.

AU - Arrighi, V.

AU - Xu, Z.

AU - Vilela, F.

PY - 2016/11/21

Y1 - 2016/11/21

N2 - BODIPY-based conjugated microporous polymers (BDP-CMP and PHTT-BDP) have been synthesised via two distinct methods of assembly: high-yielding Suzuki-Miyaura cross-coupling of BODIPY-containing building blocks, and post-synthetic conversion of an aldehyde-equipped CMP host that was synthesised in the absence of metal-based catalysts. Both approaches yielded BODIPY-based materials featuring a high BET surface area (484-769 m2 g-1) and a bathochromic shift in the maximum light absorbance (520-550 nm). Singlet oxygen production employing the BODIPY-based materials at 530 nm was carried out heterogeneously in a commercial photochemical flow reactor.

AB - BODIPY-based conjugated microporous polymers (BDP-CMP and PHTT-BDP) have been synthesised via two distinct methods of assembly: high-yielding Suzuki-Miyaura cross-coupling of BODIPY-containing building blocks, and post-synthetic conversion of an aldehyde-equipped CMP host that was synthesised in the absence of metal-based catalysts. Both approaches yielded BODIPY-based materials featuring a high BET surface area (484-769 m2 g-1) and a bathochromic shift in the maximum light absorbance (520-550 nm). Singlet oxygen production employing the BODIPY-based materials at 530 nm was carried out heterogeneously in a commercial photochemical flow reactor.

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U2 - 10.1039/c6py01393g

DO - 10.1039/c6py01393g

M3 - RGC 21 - Publication in refereed journal

SN - 1759-9954

VL - 7

SP - 6662

EP - 6670

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 43

ER -

BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor

Abstract

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