Binder-free hierarchical VS2 electrodes for high-performance aqueous Zn ion batteries towards commercial level mass loading

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

15 Scopus Citations
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Original languageEnglish
Pages (from-to)16330-16338
Journal / PublicationJournal of Materials Chemistry A
Issue number27
Online published15 Jun 2019
Publication statusPublished - 21 Jul 2019


Aqueous rechargeable zinc ion batteries with advantages of low cost and high level of safety have been considered as a promising candidate for large-scale energy storage. In this work, a freestanding, binder-free cathode comprising hierarchical VS2 in the 1T phase grown directly on a stainless steel mesh (VS2@SS) was developed for aqueous zinc ion batteries. The battery exhibited an excellent Zn ion storage capacity of 198 mA h g-1 and stable cycling performance (above 80% capacity retention over 2000 cycles at 2 A g-1). The detailed structural and chemical composition analyses revealed the phase evolution of VS2 and the reversible Zn ion insertion/extraction mechanism during the charge/discharge process. Notably, with an increased mass loading of VS2 over the commercial level (∼11 mg cm-2), a long-term cycling stability with 90% capacity retention after 600 cycles (only 0.017% loss per cycle) could be achieved, which suggests that the electrodes are promising for practical applications. Furthermore, flexible solid-state Zn ion batteries were demonstrated by using the VS2@SS electrodes, and reliable electrochemical performance could be observed even after 200 cycles.

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