Avoiding loss of catalytic activity of pd nanoparticles partially embedded in nanoditches in sic nanowires

Xiao-Ning Guo, Ru-Jing Shang, Dong-Hua Wang, Guo-Qiang Jin, Xiang-Yun Guo*, K. N. Tu*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

28 Citations (Scopus)
28 Downloads (CityUHK Scholars)

Abstract

Nanoditches from selective etching of periodically twinned SiC nanowires were employed to hinder the migration and coalescence of Pd nanoparticles supported on the nanowires, and thus to improve their catalytic stability for total combustion of methane. The results show that the etched Pd/SiC catalyst can keep the methane conversion of almost 100% while the unetched one has an obvious decline in the catalytic activity from 100 to 82% after ten repeated reaction cycles. The excellent catalytic stability originates from the limitation of the nanoditches to the migration and growth of Pd nanoparticles. © 2009 to the authors.
Original languageEnglish
Pages (from-to)332-337
JournalNanoscale Research Letters
Volume5
Issue number2
DOIs
Publication statusPublished - Feb 2010
Externally publishedYes

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Research Keywords

  • High catalytic stability
  • Pd nanoparticles
  • Selective etching
  • SiC nanowires

Publisher's Copyright Statement

  • This full text is made available under CC-BY 2.0. https://creativecommons.org/licenses/by/2.0/

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