Atomic-Scale Hidden Point-Defect Complexes Induce Ultrahigh-Irradiation Hardening in Tungsten

Tungsten displays high strength in extreme temperature and radiation environments and is considered a promising plasma facing material for fusion nuclear reactors. Unlike other metals, it experiences substantial irradiation hardening, which limits service life and presents safety concerns. The origin of ultrahigh-irradiation hardening in tungsten cannot be well-explained by conventional strengthening theories. Here, we demonstrate that irradiation leads to near 3-fold increases in strength, while the usual defects that are generated only contribute less than one-third of the hardening. An analysis of the distribution of tagged atom-helium ions reveals that more than 87% of vacancies and helium atoms are unaccounted for. A large fraction of helium-vacancy complexes are frozen in the lattice due to high vacancy migration energies. Through a combination of in situ nanomechanical tests and atomistic calculations, we provide evidence that irradiation hardening mainly originates from high densities of atomic-scale hidden point-defect complexes. © 2021 American Chemical Society.