Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal-Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes

Ya-Pan Wu; Xue-Qian Wu; Jian-Fang Wang; Jun Zhao; Wen-Wen Dong; Dong-Sheng Li; Qi-Chun Zhang

doi:10.1021/acs.cgd.6b00093

Assembly of Two Novel Cd₃/(Cd₃ + Cd₅)-Cluster-Based Metal-Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes

Ya-Pan Wu, Xue-Qian Wu, Jian-Fang Wang, Jun Zhao, Wen-Wen Dong, Dong-Sheng Li^*, Qi-Chun Zhang

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

156 Citations (Scopus)

Abstract

Two new three-dimensional (3D) multinodal Cd(II)-organic frameworks, [Cd₃(dccpa)(bipy)_0.5(H₂O)₄]·5H₂O (1) and [(CH₃)₂NH₂]₂[Cd₁₁(dccpa)₄(DMF)₄(H₂O)₈]·4H₂O (2) (H₆dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.

Original language	English
Pages (from-to)	2309-2316
Journal	Crystal Growth and Design
Volume	16
Issue number	4
Online published	14 Mar 2016
DOIs	https://doi.org/10.1021/acs.cgd.6b00093
Publication status	Published - 6 Apr 2016
Externally published	Yes

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@article{b003ed826b9e4d17ae9f9249032b7137,

title = "Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal-Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes",

abstract = "Two new three-dimensional (3D) multinodal Cd(II)-organic frameworks, [Cd3(dccpa)(bipy)0.5(H2O)4]·5H2O (1) and [(CH3)2NH2]2[Cd11(dccpa)4(DMF)4(H2O)8]·4H2O (2) (H6dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.",

author = "Ya-Pan Wu and Xue-Qian Wu and Jian-Fang Wang and Jun Zhao and Wen-Wen Dong and Dong-Sheng Li and Qi-Chun Zhang",

year = "2016",

month = apr,

day = "6",

doi = "10.1021/acs.cgd.6b00093",

language = "English",

volume = "16",

pages = "2309--2316",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "4",

}

Assembly of Two Novel Cd₃/(Cd₃ + Cd₅)-Cluster-Based Metal-Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes. / Wu, Ya-Pan; Wu, Xue-Qian; Wang, Jian-Fang et al.
In: Crystal Growth and Design, Vol. 16, No. 4, 06.04.2016, p. 2309-2316.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal-Organic Frameworks

T2 - Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes

AU - Wu, Ya-Pan

AU - Wu, Xue-Qian

AU - Wang, Jian-Fang

AU - Zhao, Jun

AU - Dong, Wen-Wen

AU - Li, Dong-Sheng

AU - Zhang, Qi-Chun

PY - 2016/4/6

Y1 - 2016/4/6

N2 - Two new three-dimensional (3D) multinodal Cd(II)-organic frameworks, [Cd3(dccpa)(bipy)0.5(H2O)4]·5H2O (1) and [(CH3)2NH2]2[Cd11(dccpa)4(DMF)4(H2O)8]·4H2O (2) (H6dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.

AB - Two new three-dimensional (3D) multinodal Cd(II)-organic frameworks, [Cd3(dccpa)(bipy)0.5(H2O)4]·5H2O (1) and [(CH3)2NH2]2[Cd11(dccpa)4(DMF)4(H2O)8]·4H2O (2) (H6dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.

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U2 - 10.1021/acs.cgd.6b00093

DO - 10.1021/acs.cgd.6b00093

M3 - RGC 21 - Publication in refereed journal

SN - 1528-7483

VL - 16

SP - 2309

EP - 2316

JO - Crystal Growth and Design

JF - Crystal Growth and Design

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