Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal-Organic Frameworks : Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 2309-2316 |
Journal / Publication | Crystal Growth and Design |
Volume | 16 |
Issue number | 4 |
Online published | 14 Mar 2016 |
Publication status | Published - 6 Apr 2016 |
Externally published | Yes |
Link(s)
Abstract
Two new three-dimensional (3D) multinodal Cd(II)-organic frameworks, [Cd3(dccpa)(bipy)0.5(H2O)4]·5H2O (1) and [(CH3)2NH2]2[Cd11(dccpa)4(DMF)4(H2O)8]·4H2O (2) (H6dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.
Citation Format(s)
Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal-Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes. / Wu, Ya-Pan; Wu, Xue-Qian; Wang, Jian-Fang et al.
In: Crystal Growth and Design, Vol. 16, No. 4, 06.04.2016, p. 2309-2316.
In: Crystal Growth and Design, Vol. 16, No. 4, 06.04.2016, p. 2309-2316.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review