An in Situ Embedded Square-Planar CuII/NiIIN4 Metalloligand in Coordination Polymers for Visible-Light Photocatalysis

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

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Original languageEnglish
Pages (from-to)2377-2380
Journal / PublicationInorganic Chemistry
Volume57
Issue number5
Online published14 Feb 2018
Publication statusPublished - 5 Mar 2018

Abstract

Three coordination polymers (CPs) with square-planar CuII/NiIIN4 subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and CuI clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.