An in Situ Embedded Square-Planar CuII/NiIIN4 Metalloligand in Coordination Polymers for Visible-Light Photocatalysis

Yun-Long Hou; Yunhong Pi; Xiao-Ping Zhou; Dan Li

doi:10.1021/acs.inorgchem.7b03068

An in Situ Embedded Square-Planar Cu^II/Ni^IIN₄ Metalloligand in Coordination Polymers for Visible-Light Photocatalysis

Yun-Long Hou, Yunhong Pi, Xiao-Ping Zhou, Dan Li^*

^*Corresponding author for this work

Department of Chemistry

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

5 Citations (Scopus)

Abstract

Three coordination polymers (CPs) with square-planar Cu^II/Ni^IIN₄ subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and Cu^I clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.

Original language	English
Pages (from-to)	2377-2380
Journal	Inorganic Chemistry
Volume	57
Issue number	5
Online published	14 Feb 2018
DOIs	https://doi.org/10.1021/acs.inorgchem.7b03068
Publication status	Published - 5 Mar 2018

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title = "An in Situ Embedded Square-Planar CuII/NiIIN4 Metalloligand in Coordination Polymers for Visible-Light Photocatalysis",

abstract = "Three coordination polymers (CPs) with square-planar CuII/NiIIN4 subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and CuI clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.",

author = "Yun-Long Hou and Yunhong Pi and Xiao-Ping Zhou and Dan Li",

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AU - Hou, Yun-Long

AU - Pi, Yunhong

AU - Zhou, Xiao-Ping

AU - Li, Dan

PY - 2018/3/5

Y1 - 2018/3/5

N2 - Three coordination polymers (CPs) with square-planar CuII/NiIIN4 subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and CuI clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.

AB - Three coordination polymers (CPs) with square-planar CuII/NiIIN4 subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and CuI clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.

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U2 - 10.1021/acs.inorgchem.7b03068

DO - 10.1021/acs.inorgchem.7b03068

M3 - RGC 21 - Publication in refereed journal

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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