An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru6(CO)12(μ3-H)(μ-CO) (μ4-η2-CO)2[η5-C5H4(SiMe3)]

Yun Chi; Chi-Jung Su; Wen-Cheng Tseng; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1023/A:1022653029796

An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru₆(CO)₁₂(μ₃-H)(μ-CO) (μ₄-η²-CO)₂[η⁵-C₅H₄(SiMe₃)]

Yun Chi
, Chi-Jung Su
, Wen-Cheng Tseng
, Shie-Ming Peng
, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

5 Citations (Scopus)

Abstract

The hexaruthenium cluster compound Ru₆(μ₃-H)(CO)₁₅[C₅H₄(SiMe₃)] (2), possessing two μ₄-η²-CO ligands and with the Ru[C₅H₄(SiMe₃)] fragment located at the apex of the central tetrahedral framework, was prepared in low yield by refluxing a toluene solution of C₅H₅(SiMe₃) with excess Ru₃(CO)₁₂. This unique complex was characterized by spectroscopic methods and by X-ray structural analysis. The possible mechanism leading to its formation is discussed.

Original language	English
Pages (from-to)	507-519
Journal	Journal of Cluster Science
Volume	8
Issue number	4
DOIs	https://doi.org/10.1023/A:1022653029796
Publication status	Published - Dec 1997
Externally published	Yes

Research Keywords

Carbonyl
Hydride
Metal cluster compound
Ruthenium
Trimethylsilylcyclopentadienyl

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Chi, Y., Su, C.-J., Tseng, W.-C., Peng, S.-M., & Lee, G.-H. (1997). An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru₆(CO)₁₂(μ₃-H)(μ-CO) (μ₄-η²-CO)₂[η⁵-C₅H₄(SiMe₃)]. Journal of Cluster Science, 8(4), 507-519. https://doi.org/10.1023/A:1022653029796

@article{2e03215a6a854162bcd0d9d63dc31325,

title = "An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru6(CO)12(μ3-H)(μ-CO) (μ4-η2-CO)2[η5-C5H4(SiMe3)]",

abstract = "The hexaruthenium cluster compound Ru6(μ3-H)(CO)15[C5H4(SiMe3)] (2), possessing two μ4-η2-CO ligands and with the Ru[C5H4(SiMe3)] fragment located at the apex of the central tetrahedral framework, was prepared in low yield by refluxing a toluene solution of C5H5(SiMe3) with excess Ru3(CO)12. This unique complex was characterized by spectroscopic methods and by X-ray structural analysis. The possible mechanism leading to its formation is discussed.",

keywords = "Carbonyl, Hydride, Metal cluster compound, Ruthenium, Trimethylsilylcyclopentadienyl",

author = "Yun Chi and Chi-Jung Su and Wen-Cheng Tseng and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1997",

month = dec,

doi = "10.1023/A:1022653029796",

language = "English",

volume = "8",

pages = "507--519",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "4",

}

Chi, Y, Su, C-J, Tseng, W-C, Peng, S-M & Lee, G-H 1997, 'An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru₆(CO)₁₂(μ₃-H)(μ-CO) (μ₄-η²-CO)₂[η⁵-C₅H₄(SiMe₃)]', Journal of Cluster Science, vol. 8, no. 4, pp. 507-519. https://doi.org/10.1023/A:1022653029796

An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands: Synthesis, Characterization, and X-Ray Structural Analysis of Ru₆(CO)₁₂(μ₃-H)(μ-CO) (μ₄-η²-CO)₂[η⁵-C₅H₄(SiMe₃)]. / Chi, Yun; Su, Chi-Jung; Tseng, Wen-Cheng et al.
In: Journal of Cluster Science, Vol. 8, No. 4, 12.1997, p. 507-519.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - An Improved Synthesis for Novel Hexaruthenium Cluster Compound Bearing Two Quadruply-Bridging CO Ligands

T2 - Synthesis, Characterization, and X-Ray Structural Analysis of Ru6(CO)12(μ3-H)(μ-CO) (μ4-η2-CO)2[η5-C5H4(SiMe3)]

AU - Chi, Yun

AU - Su, Chi-Jung

AU - Tseng, Wen-Cheng

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1997/12

Y1 - 1997/12

N2 - The hexaruthenium cluster compound Ru6(μ3-H)(CO)15[C5H4(SiMe3)] (2), possessing two μ4-η2-CO ligands and with the Ru[C5H4(SiMe3)] fragment located at the apex of the central tetrahedral framework, was prepared in low yield by refluxing a toluene solution of C5H5(SiMe3) with excess Ru3(CO)12. This unique complex was characterized by spectroscopic methods and by X-ray structural analysis. The possible mechanism leading to its formation is discussed.

AB - The hexaruthenium cluster compound Ru6(μ3-H)(CO)15[C5H4(SiMe3)] (2), possessing two μ4-η2-CO ligands and with the Ru[C5H4(SiMe3)] fragment located at the apex of the central tetrahedral framework, was prepared in low yield by refluxing a toluene solution of C5H5(SiMe3) with excess Ru3(CO)12. This unique complex was characterized by spectroscopic methods and by X-ray structural analysis. The possible mechanism leading to its formation is discussed.

KW - Carbonyl

KW - Hydride

KW - Metal cluster compound

KW - Ruthenium

KW - Trimethylsilylcyclopentadienyl

UR - https://www.scopus.com/pages/publications/0042732892

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0042732892&origin=recordpage

U2 - 10.1023/A:1022653029796

DO - 10.1023/A:1022653029796

M3 - RGC 21 - Publication in refereed journal

SN - 1040-7278

VL - 8

SP - 507

EP - 519

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -