Alkoxo-bridged Cobalt(II) Cube and Its Radical Adduct

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Author(s)

  • Kiyotaka Mitsumoto
  • Satoshi Koizumi
  • Takuya Shiga
  • Hiroyuki Nishikawa
  • Hiroki Oshio

Detail(s)

Original languageEnglish
Pages (from-to)1154-1155
Journal / PublicationChemistry Letters
Volume36
Issue number9
Online published18 Aug 2007
Publication statusPublished - 5 Sept 2007
Externally publishedYes

Link(s)

DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-34948875180&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(59876106-65c8-48cc-beec-8fab6c84215f).html

Abstract

Tetranuclear cubic complexes of [Co4(heip)4(MeOH)4] (1) and [Co4(heip)4(nit-p-py)4] (2) (H2heip = 1,1,1,5,5,5-hexafluoro-4-[(2-hydroxyethyl)imino]-2-pentanone and nit-p-py = 2-(p-pyridyl)-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide) were prepared. Complexes 1 and 2 have alkoxo-bridged cubic core structures. Magnetic susceptibility measurements revealed the occurrence of ferromagnetic interactions among CoII ions in 1, while antiferromagnetic interactions were operative in 2.

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Publication fingerprints text

100
Cobalt Chemistry
100
Antiferromagnetic Chemistry
100
Cubic Crystal Chemistry
100
Magnetic Susceptibi... Chemistry
100
Pentanone Chemistry
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Citation Format(s)

[ RIS ] [ BibTeX ]
Alkoxo-bridged Cobalt(II) Cube and Its Radical Adduct. / Mitsumoto, Kiyotaka; Koizumi, Satoshi; Shiga, Takuya et al.
In: Chemistry Letters, Vol. 36, No. 9, 05.09.2007, p. 1154-1155.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review