Aggregation and dna intercalation properties of di(isocyano) rhodium(i) Diimine complexes

Larry Tso-Lun Lo; Wing-Kin Chu; Chun-Yat Tam; Shek-Man Yiu; Chi-Chiu Ko; Sung-Kay Chiu

doi:10.1021/om200723j

Aggregation and dna intercalation properties of di(isocyano) rhodium(i) Diimine complexes

Larry Tso-Lun Lo
, Wing-Kin Chu
, Chun-Yat Tam
, Shek-Man Yiu
, Chi-Chiu Ko
, Sung-Kay Chiu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

21 Citations (Scopus)

Abstract

A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (δH) and entropy (δS) changes of dimerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay. © 2011 American Chemical Society.

Original language	English
Pages (from-to)	5873-5881
Journal	Organometallics
Volume	30
Issue number	21
DOIs	https://doi.org/10.1021/om200723j
Publication status	Published - 14 Nov 2011

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title = "Aggregation and dna intercalation properties of di(isocyano) rhodium(i) Diimine complexes",

abstract = "A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (δH) and entropy (δS) changes of dimerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay. {\textcopyright} 2011 American Chemical Society.",

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year = "2011",

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journal = "Organometallics",

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T1 - Aggregation and dna intercalation properties of di(isocyano) rhodium(i) Diimine complexes

AU - Tso-Lun Lo, Larry

AU - Chu, Wing-Kin

AU - Tam, Chun-Yat

AU - Yiu, Shek-Man

AU - Ko, Chi-Chiu

AU - Chiu, Sung-Kay

PY - 2011/11/14

Y1 - 2011/11/14

N2 - A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (δH) and entropy (δS) changes of dimerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay. © 2011 American Chemical Society.

AB - A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (δH) and entropy (δS) changes of dimerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay. © 2011 American Chemical Society.

UR - https://www.scopus.com/pages/publications/80755169622

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-80755169622&origin=recordpage

U2 - 10.1021/om200723j

DO - 10.1021/om200723j

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 30

SP - 5873

EP - 5881

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Aggregation and dna intercalation properties of di(isocyano) rhodium(i) Diimine complexes

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