Aerobic enantioselective alkene epoxidation by a chiral trans-dioxo(D4-porphyrinato)ruthenium(VI) complex

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)1583-1584
Journal / PublicationChemical Communications
Issue number15
Publication statusPublished - 7 Aug 1998

Link(s)

Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-0345420370&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(db7689bd-899d-4c5d-9712-938b688cd5cc).html

Abstract

A dioxoruthenium(VI) complex with a D4-chiral porphyrin ligand has been prepared and characterized by spectroscopic methods and X-ray crystal analysis; the complex exhibits catalytic activity towards aerobic enantioselective epoxidation of prochiral alkenes with enantioselectivity up to 73% ee at an oxygen pressure of 8 atm.

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Publication fingerprints text

100
Ruthenium Medicine & Life Sciences
99
Epoxidation Engineering & Materials S...
93
Porphyrins Medicine & Life Sciences
91
Alkenes Medicine & Life Sciences
77
Olefins Engineering & Materials S...
58
Oxygen Medicine & Life Sciences
57
Ligands Medicine & Life Sciences
48
Enantioselectivity Engineering & Materials S...
35
Catalyst activity Engineering & Materials S...
26
X rays Engineering & Materials S...
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Citation Format(s)

[ RIS ] [ BibTeX ]
Aerobic enantioselective alkene epoxidation by a chiral trans-dioxo(D4-porphyrinato)ruthenium(VI) complex. / Lai, Tat-Shing; Zhang, Rui; Cheung, Kung-Kai et al.
In: Chemical Communications, No. 15, 07.08.1998, p. 1583-1584.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review