A short-range ordered-disordered transition of a NiOOH/Ni(OH)2 pair induces switchable wettability

Ya-Huei Chang, Nga Yu Hau, Chang Liu, Yu-Ting Huang, Chien-Cheng Li, Kaimin Shih, Shien-Ping Feng*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

50 Citations (Scopus)

Abstract

By virtue of its amorphous structure with a short-range order feature, the inorganic nanoporous nickel oxyhydroxide (NiOOH) can reversibly and rapidly switch wettability by alternate treatments of environmental chamber (superhydrophobic) and UV/ozone (superhydrophilic). The switchable mechanism of the NiOOH/Ni(OH)2 pair arising from its exceptional intrinsic short-range order-disorder transition together with chemical composition change is highlighted for the first time, which significantly differs from the current stimuli-responsive materials. This distinct multifunctional thin film not only possesses reversible wettability but also is optically patternable/repairable and electrically conductive, which could be applicable in the manufacturing of various micro- and nanostructures. We demonstrate this potential in the rewritable two-dimensional (2D) microfluidic channels and wetting-contrast enhanced selective electroplating. This journal is
Original languageEnglish
Pages (from-to)15309-15315
JournalNanoscale
Volume6
Issue number24
DOIs
Publication statusPublished - 21 Dec 2014
Externally publishedYes

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