TY - JOUR
T1 - A short-range ordered-disordered transition of a NiOOH/Ni(OH)2 pair induces switchable wettability
AU - Chang, Ya-Huei
AU - Hau, Nga Yu
AU - Liu, Chang
AU - Huang, Yu-Ting
AU - Li, Chien-Cheng
AU - Shih, Kaimin
AU - Feng, Shien-Ping
N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].
PY - 2014/12/21
Y1 - 2014/12/21
N2 - By virtue of its amorphous structure with a short-range order feature, the inorganic nanoporous nickel oxyhydroxide (NiOOH) can reversibly and rapidly switch wettability by alternate treatments of environmental chamber (superhydrophobic) and UV/ozone (superhydrophilic). The switchable mechanism of the NiOOH/Ni(OH)2 pair arising from its exceptional intrinsic short-range order-disorder transition together with chemical composition change is highlighted for the first time, which significantly differs from the current stimuli-responsive materials. This distinct multifunctional thin film not only possesses reversible wettability but also is optically patternable/repairable and electrically conductive, which could be applicable in the manufacturing of various micro- and nanostructures. We demonstrate this potential in the rewritable two-dimensional (2D) microfluidic channels and wetting-contrast enhanced selective electroplating. This journal is
AB - By virtue of its amorphous structure with a short-range order feature, the inorganic nanoporous nickel oxyhydroxide (NiOOH) can reversibly and rapidly switch wettability by alternate treatments of environmental chamber (superhydrophobic) and UV/ozone (superhydrophilic). The switchable mechanism of the NiOOH/Ni(OH)2 pair arising from its exceptional intrinsic short-range order-disorder transition together with chemical composition change is highlighted for the first time, which significantly differs from the current stimuli-responsive materials. This distinct multifunctional thin film not only possesses reversible wettability but also is optically patternable/repairable and electrically conductive, which could be applicable in the manufacturing of various micro- and nanostructures. We demonstrate this potential in the rewritable two-dimensional (2D) microfluidic channels and wetting-contrast enhanced selective electroplating. This journal is
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U2 - 10.1039/c4nr05261g
DO - 10.1039/c4nr05261g
M3 - RGC 21 - Publication in refereed journal
SN - 2040-3364
VL - 6
SP - 15309
EP - 15315
JO - Nanoscale
JF - Nanoscale
IS - 24
ER -