A polymeric flame retardant and surfactant-free montmorillonite nanocomposites : Preparation and exfoliation mechanism discussion

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

18 Scopus Citations
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Author(s)

  • Qilong Tai
  • Xueying Shan
  • Lei Song
  • Yuan Hu

Detail(s)

Original languageEnglish
Pages (from-to)167-173
Journal / PublicationPolymer Composites
Volume35
Issue number1
Online published6 Sept 2013
Publication statusPublished - Jan 2014

Abstract

A polymeric flame retardant (PDEPD) and various amounts of sodium montmorillonite (Na-MMT) nanocomposites with exfoliation structure were prepared via one-step polycondensation, attempting to prepare flame-retardant nanocomposites. The nanocomposites exhibited high thermal stability at high temperature. Based on several comparative studies, we investigated and proposed the possible exfoliation mechanism of Na-MMT in PDEPD substrate. The microscale combustion calorimeter and cone calorimeter results showed the PDEPD/Na-MMT nanocomposites could significantly improve the flame retardancy of polystyrene and polyurethane elastomer (TPU), especially the TPU matrix. This study provides new viewpoint for preparing flame-retardant nanocomposites without surfactants. © 2013 Society of Plastics Engineers.