A p-type Ti(IV)-based metal–organic framework with visible-light photo-response

Junkuo Gao; Jianwei Miao; Pei-Zhou Li; Wen Yuan Teng; Ling Yang; Yanli Zhao; Bin Liu; Qichun Zhang

doi:10.1039/c3cc49440c

A p-type Ti(IV)-based metal–organic framework with visible-light photo-response

Junkuo Gao, Jianwei Miao, Pei-Zhou Li, Wen Yuan Teng, Ling Yang, Yanli Zhao, Bin Liu^*, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

442 Citations (Scopus)

Abstract

Here, we report a new Ti(IV)-based porous metal–organic framework (MOF) (NTU-9), which displayed strong absorption in the visible region with a bandgap of 1.72 eV. The electronic structure and bandgap were further investigated by DFT calculations. Photoelectrochemical studies indicated that NTU-9 is photoactive under visible light illumination (λ > 400 nm) and acts as a p-type semiconductor. The results demonstrated that Ti(IV)-based MOFs could be promising visible-light photocatalysts for energy conversion and environmental remediation. © The Royal Society of Chemistry 2014.

Original language	English
Pages (from-to)	3786-3788
Journal	Chemical Communications
Volume	50
Issue number	29
Online published	4 Feb 2014
DOIs	https://doi.org/10.1039/c3cc49440c
Publication status	Published - 14 Apr 2014
Externally published	Yes

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@article{6f2a0d40fd5b417a93177ff00ee2b4e8,

title = "A p-type Ti(IV)-based metal–organic framework with visible-light photo-response",

abstract = "Here, we report a new Ti(IV)-based porous metal–organic framework (MOF) (NTU-9), which displayed strong absorption in the visible region with a bandgap of 1.72 eV. The electronic structure and bandgap were further investigated by DFT calculations. Photoelectrochemical studies indicated that NTU-9 is photoactive under visible light illumination (λ > 400 nm) and acts as a p-type semiconductor. The results demonstrated that Ti(IV)-based MOFs could be promising visible-light photocatalysts for energy conversion and environmental remediation. {\textcopyright} The Royal Society of Chemistry 2014.",

author = "Junkuo Gao and Jianwei Miao and Pei-Zhou Li and Teng, {Wen Yuan} and Ling Yang and Yanli Zhao and Bin Liu and Qichun Zhang",

year = "2014",

month = apr,

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doi = "10.1039/c3cc49440c",

language = "English",

volume = "50",

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journal = "Chemical Communications",

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TY - JOUR

T1 - A p-type Ti(IV)-based metal–organic framework with visible-light photo-response

AU - Gao, Junkuo

AU - Miao, Jianwei

AU - Li, Pei-Zhou

AU - Teng, Wen Yuan

AU - Yang, Ling

AU - Zhao, Yanli

AU - Liu, Bin

AU - Zhang, Qichun

PY - 2014/4/14

Y1 - 2014/4/14

N2 - Here, we report a new Ti(IV)-based porous metal–organic framework (MOF) (NTU-9), which displayed strong absorption in the visible region with a bandgap of 1.72 eV. The electronic structure and bandgap were further investigated by DFT calculations. Photoelectrochemical studies indicated that NTU-9 is photoactive under visible light illumination (λ > 400 nm) and acts as a p-type semiconductor. The results demonstrated that Ti(IV)-based MOFs could be promising visible-light photocatalysts for energy conversion and environmental remediation. © The Royal Society of Chemistry 2014.

AB - Here, we report a new Ti(IV)-based porous metal–organic framework (MOF) (NTU-9), which displayed strong absorption in the visible region with a bandgap of 1.72 eV. The electronic structure and bandgap were further investigated by DFT calculations. Photoelectrochemical studies indicated that NTU-9 is photoactive under visible light illumination (λ > 400 nm) and acts as a p-type semiconductor. The results demonstrated that Ti(IV)-based MOFs could be promising visible-light photocatalysts for energy conversion and environmental remediation. © The Royal Society of Chemistry 2014.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84896273976&origin=recordpage

U2 - 10.1039/c3cc49440c

DO - 10.1039/c3cc49440c

M3 - RGC 21 - Publication in refereed journal

C2 - 24522830

SN - 1359-7345

VL - 50

SP - 3786

EP - 3788

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

A p-type Ti(IV)-based metal–organic framework with visible-light photo-response

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