A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang; Wai-Lun Man; Junfang Guo; Shek-Man Yiu; Gene-Hsiang Lee; Shie-Ming Peng; Guancheng Xu; Song Gao; Tai-Chu Lau

doi:10.1039/c001732a

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang
, Wai-Lun Man
, Junfang Guo
, Shek-Man Yiu
, Gene-Hsiang Lee
, Shie-Ming Peng
, Guancheng Xu
, Song Gao
, Tai-Chu Lau

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

27 Citations (Scopus)

Abstract

Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-Ru^III magnetic materials. © 2010 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	6102-6104
Journal	Chemical Communications
Volume	46
Issue number	33
DOIs	https://doi.org/10.1039/c001732a
Publication status	Published - 7 Sept 2010

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title = "A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers",

abstract = "Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials. {\textcopyright} 2010 The Royal Society of Chemistry.",

author = "Jing Xiang and Wai-Lun Man and Junfang Guo and Shek-Man Yiu and Gene-Hsiang Lee and Shie-Ming Peng and Guancheng Xu and Song Gao and Tai-Chu Lau",

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journal = "Chemical Communications",

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TY - JOUR

T1 - A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

AU - Xiang, Jing

AU - Man, Wai-Lun

AU - Guo, Junfang

AU - Yiu, Shek-Man

AU - Lee, Gene-Hsiang

AU - Peng, Shie-Ming

AU - Xu, Guancheng

AU - Gao, Song

AU - Lau, Tai-Chu

PY - 2010/9/7

Y1 - 2010/9/7

N2 - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials. © 2010 The Royal Society of Chemistry.

AB - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials. © 2010 The Royal Society of Chemistry.

UR - https://www.scopus.com/pages/publications/77955838709

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-77955838709&origin=recordpage

U2 - 10.1039/c001732a

DO - 10.1039/c001732a

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 46

SP - 6102

EP - 6104

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

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