A novel lattice-hardening process to achieve highly efficient and thermally stable nonlinear optical polymers

Marnie Haller; Jingdong Luo; Hongxiang Li; Tae-Dong Kim; Yi Liao; Bruce H. Robinson; Larry R. Dalton; Alex K.-Y. Jen

doi:10.1021/ma035393b

A novel lattice-hardening process to achieve highly efficient and thermally stable nonlinear optical polymers

Marnie Haller, Jingdong Luo, Hongxiang Li, Tae-Dong Kim, Yi Liao, Bruce H. Robinson, Larry R. Dalton, Alex K.-Y. Jen

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

96 Citations (Scopus)

Abstract

High poling efficiency of a thermoplastic can be achieved while maintain thermal stability of a densely cross-linked polymer through the novel Diels-Alder lattice-hardening process. Thus, the resultant materials exhibit large r₃₃ values and good temporal stability at 85 °C. Furthermore, it allows to fine-tune processing temperature and reversibility of these Diels-Alder reactions to optimize thermal stability and processability by modifying the electronic properties of the cross-linking reagents.

Original language	English
Pages (from-to)	688-690
Journal	Macromolecules
Volume	37
Issue number	3
Online published	14 Jan 2004
DOIs	https://doi.org/10.1021/ma035393b
Publication status	Published - 1 Feb 2004
Externally published	Yes

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abstract = "High poling efficiency of a thermoplastic can be achieved while maintain thermal stability of a densely cross-linked polymer through the novel Diels-Alder lattice-hardening process. Thus, the resultant materials exhibit large r33 values and good temporal stability at 85 °C. Furthermore, it allows to fine-tune processing temperature and reversibility of these Diels-Alder reactions to optimize thermal stability and processability by modifying the electronic properties of the cross-linking reagents.",

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T1 - A novel lattice-hardening process to achieve highly efficient and thermally stable nonlinear optical polymers

AU - Haller, Marnie

AU - Luo, Jingdong

AU - Li, Hongxiang

AU - Kim, Tae-Dong

AU - Liao, Yi

AU - Robinson, Bruce H.

AU - Dalton, Larry R.

AU - Jen, Alex K.-Y.

PY - 2004/2/1

Y1 - 2004/2/1

N2 - High poling efficiency of a thermoplastic can be achieved while maintain thermal stability of a densely cross-linked polymer through the novel Diels-Alder lattice-hardening process. Thus, the resultant materials exhibit large r33 values and good temporal stability at 85 °C. Furthermore, it allows to fine-tune processing temperature and reversibility of these Diels-Alder reactions to optimize thermal stability and processability by modifying the electronic properties of the cross-linking reagents.

AB - High poling efficiency of a thermoplastic can be achieved while maintain thermal stability of a densely cross-linked polymer through the novel Diels-Alder lattice-hardening process. Thus, the resultant materials exhibit large r33 values and good temporal stability at 85 °C. Furthermore, it allows to fine-tune processing temperature and reversibility of these Diels-Alder reactions to optimize thermal stability and processability by modifying the electronic properties of the cross-linking reagents.

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U2 - 10.1021/ma035393b

DO - 10.1021/ma035393b

M3 - RGC 21 - Publication in refereed journal

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VL - 37

SP - 688

EP - 690

JO - Macromolecules

JF - Macromolecules

IS - 3

ER -

A novel lattice-hardening process to achieve highly efficient and thermally stable nonlinear optical polymers

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