A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions : {[Ni(cyclen)] [Ag(CN)2]} [Ag(CN)2]

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

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Author(s)

  • Iris P. Y. Shek
  • Wai-Yeung Wong
  • Tai-Chu Lau

Detail(s)

Original languageEnglish
Pages (from-to)733-734
Journal / PublicationNew Journal of Chemistry
Volume24
Issue number10
Online published15 Sep 2000
Publication statusPublished - 2000

Link(s)

DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-0033774988&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(5bd68546-edcd-4496-8896-dfce871c599a).html

Abstract

Reaction of nickel(II) acetate with cyclen (cyelen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)2] gave {[Ni(cyclen)]-[Ag(CN)2]} [Ag(CN)2], which consists of cis-[Ni(cyclen)]2+ units bridged by [Ag(CN)2]- to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)2]- also align together to form an infinite zig-zag chain with short Ag···Ag distances.

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Nickel Engineering & Materials S...
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Atoms Engineering & Materials S...
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Polymers Engineering & Materials S...
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Citation Format(s)

[ RIS ] [ BibTeX ]

A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions : {[Ni(cyclen)] [Ag(CN)2]} [Ag(CN)2]. / Shek, Iris P. Y.; Wong, Wai-Yeung; Lau, Tai-Chu.

In: New Journal of Chemistry, Vol. 24, No. 10, 2000, p. 733-734.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review