A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co4(μ3-OH)2] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand

Junhua Luo; Yusheng Zhao; Hongwu Xu; Tiffany L. Kinnibrugh; Dali Yang; Tatiana V. Timofeeva; Luke L. Daemen; Jianzhong Zhang; Wei Bao; Joe D. Thompson; Robert P. Currier

doi:10.1021/ic701003z

A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co₄(μ₃-OH)₂] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand

Junhua Luo^*, Yusheng Zhao^*, Hongwu Xu, Tiffany L. Kinnibrugh, Dali Yang, Tatiana V. Timofeeva, Luke L. Daemen, Jianzhong Zhang, Wei Bao, Joe D. Thompson, Robert P. Currier

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

90 Citations (Scopus)

Abstract

A novel cobalt(ll)-organic framework, [Co₂(OH)(3,4-PBC)₃]_n(I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [Co^II₄(μ₃-OH)₂] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

Original language	English
Pages (from-to)	9021-9023
Journal	Inorganic Chemistry
Volume	46
Issue number	22
Online published	22 Sept 2007
DOIs	https://doi.org/10.1021/ic701003z
Publication status	Published - 1 Oct 2007
Externally published	Yes

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Luo, J., Zhao, Y., Xu, H., Kinnibrugh, T. L., Yang, D., Timofeeva, T. V., Daemen, L. L., Zhang, J., Bao, W., Thompson, J. D., & Currier, R. P. (2007). A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co₄(μ₃-OH)₂] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand. Inorganic Chemistry, 46(22), 9021-9023. https://doi.org/10.1021/ic701003z

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title = "A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co4(μ3-OH)2] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand",

abstract = "A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC)3]n(I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.",

author = "Junhua Luo and Yusheng Zhao and Hongwu Xu and Kinnibrugh, {Tiffany L.} and Dali Yang and Timofeeva, {Tatiana V.} and Daemen, {Luke L.} and Jianzhong Zhang and Wei Bao and Thompson, {Joe D.} and Currier, {Robert P.}",

year = "2007",

month = oct,

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doi = "10.1021/ic701003z",

language = "English",

volume = "46",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co₄(μ₃-OH)₂] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand. / Luo, Junhua; Zhao, Yusheng; Xu, Hongwu et al.
In: Inorganic Chemistry, Vol. 46, No. 22, 01.10.2007, p. 9021-9023.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - A Novel Helical Double-Layered Cobalt(ll)-Organic Framework with Tetranuclear [Co4(μ3-OH)2] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand

AU - Luo, Junhua

AU - Zhao, Yusheng

AU - Xu, Hongwu

AU - Kinnibrugh, Tiffany L.

AU - Yang, Dali

AU - Timofeeva, Tatiana V.

AU - Daemen, Luke L.

AU - Zhang, Jianzhong

AU - Bao, Wei

AU - Thompson, Joe D.

AU - Currier, Robert P.

PY - 2007/10/1

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N2 - A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC)3]n(I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

AB - A novel cobalt(ll)-organic framework, [Co2(OH)(3,4-PBC)3]n(I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

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M3 - RGC 21 - Publication in refereed journal

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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