A novel D0₂₂-strengthened medium entropy alloy with outstanding strength-ductility synergies over ambient and intermediate temperatures

Precipitation-strengthened medium/high-entropy alloys (MEAs/HEAs) have great potential for high-temperature applications. In this study, we designed a novel Ni_45.9Fe₂₃Cr₂₃V₄Nb₃Mo₁B_0.1 (at.%) MEA alloy, hardened by the D0₂₂ (Ni, Fe, Cr)₃(Nb, V)-type nanoprecipitates, with an excellent strength-ductility combination from room to elevated temperatures. Specifically, the tensile strengths, at 700 and 800 °C, could be maintained as high as 845 and 589 MPa, respectively; meanwhile, elongations at all testing temperatures exceeded 25 % without any intermediate-temperature embrittlement. The temperature-dependent deformation mechanisms were unraveled using multi-scale characterizations, which involved profound slip planarities, such as stacking fault (SF) networks and deformation twins (DTs). Furthermore, the critical resolved shear stress (CRSS) to initiate SFs in both face-centered cubic (FCC) and D0₂₂ phases was evaluated, and the possible reasons for the origin of anomalous DTs at 800 °C were discussed in detail. The main findings demonstrate that the shearable D0₂₂ nanoparticles can provide the FCC matrix with considerable dislocation storage capacity, reinforcing strain hardening at ambient and intermediate temperatures. This work provides fundamental insights into the controllable design and deformation mechanisms of high-performance D0₂₂-strengthened MEAs/HEAs.

© 2024 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.