A note on the effects of inorganic seed aerosol on the oxidation state of secondary organic aerosol—α-Pinene ozonolysis

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Dan Dan Huang
  • Xuan Zhang
  • Nathan F. Dalleska
  • Hanna Lignell
  • Matthew M. Coggon
  • Chi-Ming Chan
  • Richard C. Flagan
  • John H. Seinfeld

Related Research Unit(s)

Detail(s)

Original languageEnglish
Pages (from-to)12,476-12,483
Journal / PublicationJournal of Geophysical Research: Atmospheres
Volume121
Issue number20
Publication statusPublished - 27 Oct 2016

Abstract

We compare the oxidation state and molecular composition of α-pinene-derived secondary organic aerosol (SOA) by varying the types and surface areas of inorganic seed aerosol that are used to promote the condensation of SOA-forming vapors. The oxidation state of α-pinene SOA is found to increase with inorganic seed surface area, likely a result of enhanced condensation of low-volatility organic compounds on particles versus deposition on the chamber wall. α-Pinene SOA is more highly oxygenated in the presence of sodium nitrate (SN) seed than ammonium sulfate seed. The relative abundance of semivolatile monomers and low-volatility dimer components that account for more than half of α-pinene SOA mass is not significantly affected by the composition of seed aerosol. Enhanced uptake of highly oxidized small carboxylic acids onto SN seed particles is observed, which could potentially explain the observed higher SOA oxidation state in the presence of SN seed aerosol. Overall, our results demonstrate that a combined effect of seed aerosol composition and surface area leads to an increase in the O:C atomic ratio of α-pinene SOA by as much as a factor of 2.

Research Area(s)

  • aerosol oxidation state, highly oxygenated small carboxylic acids, inorganic seed aerosol

Citation Format(s)

A note on the effects of inorganic seed aerosol on the oxidation state of secondary organic aerosol—α-Pinene ozonolysis. / Huang, Dan Dan; Zhang, Xuan; Dalleska, Nathan F.; Lignell, Hanna; Coggon, Matthew M.; Chan, Chi-Ming; Flagan, Richard C.; Seinfeld, John H.; Chan, Chak K.

In: Journal of Geophysical Research: Atmospheres, Vol. 121, No. 20, 27.10.2016, p. 12,476-12,483.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review