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Abstract
A new tetradentate mixed aza-thioether macrocyclic ligand 2,6-dithia[7](2,9)-1,10-phenanthrolinophane ([13]ane(phenN2)S2) was successfully synthesized. Reacting metal precursors [Fe(CH3CN)2(OTf)2], Ni(ClO4)2·6H2O, and Cu(ClO4)2·6H2O with one equivalent of [13]ane(phenN2)S2 afforded [Fe([13]ane(phenN2)S2)(OTf)2] (1), [Ni([13]ane(phenN2)S2)](ClO4)2 (2(ClO4)2), and [Cu([13]ane(phenN2)S2)(OH2)](ClO4)2 (3(ClO4)2), respectively. The structures of [13]ane(phenN2)S2 and all of its metal complexes were investigated by X-ray crystallography. The [13]ane(phenN2)S2 was found to behave as a tetradentate ligand via its donor atoms N and S.
| Original language | English |
|---|---|
| Article number | 2030 |
| Number of pages | 15 |
| Journal | Molecules |
| Volume | 25 |
| Issue number | 9 |
| Online published | 27 Apr 2020 |
| DOIs | |
| Publication status | Published - 1 May 2020 |
Research Keywords
- Coordination complex
- First-row transition metal ion
- Macrocyclic ligand
Publisher's Copyright Statement
- This full text is made available under CC-BY 4.0. https://creativecommons.org/licenses/by/4.0/
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Dive into the research topics of 'A New Tetradentate Mixed Aza-Thioether Macrocycle and Its Complexation Behavior towards Fe(II), Ni(II) and Cu(II) Ions'. Together they form a unique fingerprint.Projects
- 2 Finished
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GRF: Rational Design of Photoresponsive Anti-Cancer Drug Delivery Nanoparticles
WONG, C. Y. A. (Principal Investigator / Project Coordinator) & LEUNG, D.C.-H. (Co-Investigator)
1/01/18 → 6/12/21
Project: Research
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TBRS: A Compact System for Terahertz Imaging and Spectroscopy
CHAN, C. H. (Principal Investigator / Project Coordinator), LO, K. W. K. (Co-Principal Investigator), LUK, K. M. (Co-Principal Investigator), PUN, Y. B. E. (Co-Principal Investigator), Pang, S. (Co-Principal Investigator), SHAW, J. (Co-Principal Investigator), VELLAISAMY, A. L. R. (Co-Principal Investigator), CHAN, S. C. (Co-Investigator), DECROZE, C. (Co-Investigator), HO, J. C. Y. (Co-Investigator), JARRAHI, M. (Co-Investigator), LAM, Y. W. (Co-Investigator), LEE, E.-Y. J. (Co-Investigator), LEE, N. P. Y. (Co-Investigator), LEUNG, K. W. (Co-Investigator), LIU, H. (Co-Investigator), QU, S. (Co-Investigator), RENAUD, C. (Co-Investigator), Tong, K. (Co-Investigator), WANG, C. (Co-Investigator), WONG, H. (Co-Investigator), WONG, C. Y. A. (Co-Investigator), WONG, M. H. A. (Co-Investigator) & Wong, K. K. Y. (Co-Investigator)
1/01/17 → 30/06/23
Project: Research