A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks

Jun Zhao; Yenan Wang; Wenwen Dong; Yapan Wu; Dongsheng Li; Bin Liu; Qichun Zhang

doi:10.1039/c5cc02043c

A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks

Jun Zhao, Yenan Wang, Wenwen Dong, Yapan Wu, Dongsheng Li^*, Bin Liu^*, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

152 Citations (Scopus)

Abstract

By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.5²}₂{4².5⁶.6¹⁴.7².8⁴} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {6².10³.12}{6³}₂{6⁴.8.10}₂ topological net.

Original language	English
Pages (from-to)	9479-9482
Journal	Chemical Communications
Volume	51
Issue number	46
Online published	27 Apr 2015
DOIs	https://doi.org/10.1039/c5cc02043c
Publication status	Published - 11 Jun 2015
Externally published	Yes

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title = "A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks",

abstract = "By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.",

author = "Jun Zhao and Yenan Wang and Wenwen Dong and Yapan Wu and Dongsheng Li and Bin Liu and Qichun Zhang",

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T1 - A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks

AU - Zhao, Jun

AU - Wang, Yenan

AU - Dong, Wenwen

AU - Wu, Yapan

AU - Li, Dongsheng

AU - Liu, Bin

AU - Zhang, Qichun

PY - 2015/6/11

Y1 - 2015/6/11

N2 - By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.

AB - By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.

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U2 - 10.1039/c5cc02043c

DO - 10.1039/c5cc02043c

M3 - RGC 21 - Publication in refereed journal

SN - 1359-7345

VL - 51

SP - 9479

EP - 9482

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks

Abstract

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