TY - JOUR
T1 - A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks
AU - Zhao, Jun
AU - Wang, Yenan
AU - Dong, Wenwen
AU - Wu, Yapan
AU - Li, Dongsheng
AU - Liu, Bin
AU - Zhang, Qichun
PY - 2015/6/11
Y1 - 2015/6/11
N2 - By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.
AB - By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)-MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.
UR - http://www.scopus.com/inward/record.url?scp=84930205522&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84930205522&origin=recordpage
U2 - 10.1039/c5cc02043c
DO - 10.1039/c5cc02043c
M3 - RGC 21 - Publication in refereed journal
SN - 1359-7345
VL - 51
SP - 9479
EP - 9482
JO - Chemical Communications
JF - Chemical Communications
IS - 46
ER -