Abstract
Blue-emitting complexes: Iridium complexes exhibit dual phosphorescence. The blue phosphorescence at room temperature, attributed to TILCT→TLLCT conversion, occurs via a high energy barrier (∼6.9 kcal mol-1) resuiting from large-amplitude motions, such as partial twisting of the chelate groups which flip the orbital configuration and consequently results in dual phosphorescence.
| Original language | English |
|---|---|
| Pages (from-to) | 2294-2297 |
| Journal | ChemPhysChem |
| Volume | 7 |
| Issue number | 11 |
| Online published | 6 Nov 2006 |
| DOIs | |
| Publication status | Published - 13 Nov 2006 |
| Externally published | Yes |
Research Keywords
- Charge transfer
- Density functional calculations
- Iridium
- Osmium
- UV/Vis spectroscopy
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