A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties

Chi-On Ng; Larry Tso-Lun Lo; Siu-Mui Ng; Chi-Chiu Ko; Nianyong Zhu

doi:10.1021/ic800906x

A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties

Chi-On Ng
, Larry Tso-Lun Lo
, Siu-Mui Ng
, Chi-Chiu Ko
, Nianyong Zhu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

52 Citations (Scopus)

Abstract

A new class of readily tunable and highly environmentally sensitive luminescent rhenium(1) tetra(isocyano)bipyridyl complexes has been synthesized and characterized, and their luminescent properties have been investigated. Preliminary studies showed that the metal-to-ligand charge-transfer [dπ(Re) → π* (bpy)] absorption and emission are extremely sensitive to the nature of the solvent and the rigidity of the environment. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	7447-7449
Journal	Inorganic Chemistry
Volume	47
Issue number	17
DOIs	https://doi.org/10.1021/ic800906x
Publication status	Published - 1 Sept 2008

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title = "A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties",

abstract = "A new class of readily tunable and highly environmentally sensitive luminescent rhenium(1) tetra(isocyano)bipyridyl complexes has been synthesized and characterized, and their luminescent properties have been investigated. Preliminary studies showed that the metal-to-ligand charge-transfer [dπ(Re) → π* (bpy)] absorption and emission are extremely sensitive to the nature of the solvent and the rigidity of the environment. {\textcopyright} 2008 American Chemical Society.",

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A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties. / Ng, Chi-On; Lo, Larry Tso-Lun; Ng, Siu-Mui et al.
In: Inorganic Chemistry, Vol. 47, No. 17, 01.09.2008, p. 7447-7449.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties

AU - Ng, Chi-On

AU - Lo, Larry Tso-Lun

AU - Ng, Siu-Mui

AU - Ko, Chi-Chiu

AU - Zhu, Nianyong

PY - 2008/9/1

Y1 - 2008/9/1

N2 - A new class of readily tunable and highly environmentally sensitive luminescent rhenium(1) tetra(isocyano)bipyridyl complexes has been synthesized and characterized, and their luminescent properties have been investigated. Preliminary studies showed that the metal-to-ligand charge-transfer [dπ(Re) → π* (bpy)] absorption and emission are extremely sensitive to the nature of the solvent and the rigidity of the environment. © 2008 American Chemical Society.

AB - A new class of readily tunable and highly environmentally sensitive luminescent rhenium(1) tetra(isocyano)bipyridyl complexes has been synthesized and characterized, and their luminescent properties have been investigated. Preliminary studies showed that the metal-to-ligand charge-transfer [dπ(Re) → π* (bpy)] absorption and emission are extremely sensitive to the nature of the solvent and the rigidity of the environment. © 2008 American Chemical Society.

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U2 - 10.1021/ic800906x

DO - 10.1021/ic800906x

M3 - RGC 21 - Publication in refereed journal

C2 - 18661968

SN - 0020-1669

VL - 47

SP - 7447

EP - 7449

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

A new class of isocyanide-containing rhenium(I) bipyridyl luminophore with readily tunable and highly environmentally sensitive excited-state properties

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