A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

Qiang Dong; - NARENTUOYA; Lei Zhang; Weixuan JIANG; Miaomiao Xue; Xiang Wang; Libao Chen; Chun-Sing Lee; Qichun Zhang

doi:10.1002/anie.202405426

A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

Qiang Dong, - NARENTUOYA, Lei Zhang, Weixuan JIANG, Miaomiao Xue, Xiang Wang, Libao Chen^*, Chun-Sing Lee, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

36 Citations (Scopus)

28 Downloads (CityUHK Scholars)

Abstract

Inspired by dative boron-nitrogen (B←N) bonds proven to be the promising dynamic linkage for the construction of crystalline covalent organic polymers/frameworks (COPs/COFs), we employed 1,4-bis(benzodioxaborole) benzene (BACT) and N,N′-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide (DPNTCDI) as the corresponding building blocks to construct a functional COP (named as CityU-25), which had been employed as an anode in rechargeable lithium ion batteries. CityU-25 displayed an excellent reversible lithium storage capability of 455 mAh/g after 170 cycles at 0.1 A/g, and an impressive one of 673 mAh/g after 720 cycles at 0.5 A/g. These findings suggest that CityU-25 is a standout candidate for advanced battery technologies, highlighting the potential application of this type of materials. © 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

Original language	English
Article number	e202405426
Journal	Angewandte Chemie (International Edition)
Volume	63
Issue number	26
Online published	19 Apr 2024
DOIs	https://doi.org/10.1002/anie.202405426
Publication status	Published - 21 Jun 2024

Funding

Q. Z. acknowledges the funding support from the City University of Hong Kong (9380117 and 7020089) Hong Kong, P. R. China. C. S. L. and Q. Z. thanks the funding support from the Innovation and Technology Fund (ITF, ITS/322/22). Q. Z. also thanks the funding support from State Key Laboratory of Supramolecular Structure and Materials, Jilin University (sklssm2024039), P. R. China.

Research Keywords

dative boron-nitrogen bonds
covalent organic polymer
single crystal structure
lithium ion battery

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This full text is made available under CC-BY 4.0. https://creativecommons.org/licenses/by/4.0/

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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abstract = "Inspired by dative boron-nitrogen (B←N) bonds proven to be the promising dynamic linkage for the construction of crystalline covalent organic polymers/frameworks (COPs/COFs), we employed 1,4-bis(benzodioxaborole) benzene (BACT) and N,N′-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide (DPNTCDI) as the corresponding building blocks to construct a functional COP (named as CityU-25), which had been employed as an anode in rechargeable lithium ion batteries. CityU-25 displayed an excellent reversible lithium storage capability of 455 mAh/g after 170 cycles at 0.1 A/g, and an impressive one of 673 mAh/g after 720 cycles at 0.5 A/g. These findings suggest that CityU-25 is a standout candidate for advanced battery technologies, highlighting the potential application of this type of materials. {\textcopyright} 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.",

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A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application. / Dong, Qiang ; NARENTUOYA, -; Zhang, Lei et al.
In: Angewandte Chemie (International Edition), Vol. 63, No. 26, e202405426, 21.06.2024.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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AU - Zhang, Lei

AU - JIANG, Weixuan

AU - Xue, Miaomiao

AU - Wang, Xiang

AU - Chen, Libao

AU - Lee, Chun-Sing

AU - Zhang, Qichun

PY - 2024/6/21

Y1 - 2024/6/21

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AB - Inspired by dative boron-nitrogen (B←N) bonds proven to be the promising dynamic linkage for the construction of crystalline covalent organic polymers/frameworks (COPs/COFs), we employed 1,4-bis(benzodioxaborole) benzene (BACT) and N,N′-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide (DPNTCDI) as the corresponding building blocks to construct a functional COP (named as CityU-25), which had been employed as an anode in rechargeable lithium ion batteries. CityU-25 displayed an excellent reversible lithium storage capability of 455 mAh/g after 170 cycles at 0.1 A/g, and an impressive one of 673 mAh/g after 720 cycles at 0.5 A/g. These findings suggest that CityU-25 is a standout candidate for advanced battery technologies, highlighting the potential application of this type of materials. © 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

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A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

Abstract

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Research Keywords

Publisher's Copyright Statement

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ITF: High Performance All-organic Rechargeable Sodium-ion Batteries Based on Covalent Organic Frameworks

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A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

Abstract

Funding

Research Keywords

Publisher's Copyright Statement

UN SDGs

Access Output

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Permanent Link

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Projects

ITF: High Performance All-organic Rechargeable Sodium-ion Batteries Based on Covalent Organic Frameworks

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