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A metastable phase of tin in 3D integrated circuit solder microbumps

  • Yingxia Liu
  • , Nobumichi Tamura
  • , Dong Wook Kim
  • , Sam Gu
  • , K. N. Tu*
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

A metastable phase of Sn has been found to co-exist with β-Sn in Pb-free SnAg microbumps in 3D integrated circuit technology. Synchrotron microbeam X-ray diffraction, high-resolution TEM imaging and selected-area electron diffraction were used to confirm the metastable phase, which has an orthorhombic lattice, with lattice parameter a = 0.635 nm, b = 0.639 nm, and c = 1.147 nm. Its composition is Sn containing a few percent of Ni. A higher rate of nucleation might have enabled its formation.
Original languageEnglish
Pages (from-to)39-42
JournalScripta Materialia
Volume102
Online published24 Feb 2015
DOIs
Publication statusPublished - Jun 2015
Externally publishedYes

Research Keywords

  • Electronic packaging
  • Lead-free solder
  • Metastable phases
  • Joining

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