A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide

X. M. Qian; K. C. Lau; C. Y. Ng

doi:10.1063/1.1739402

Author(s)

X. M. Qian
K. C. Lau
C. Y. Ng

Detail(s)

Original language	English
Pages (from-to)	11031-11041
Journal / Publication	Journal of Chemical Physics
Volume	120
Issue number	23
Publication status	Published - 15 Jun 2004
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1063/1.1739402 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-3042644536&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(ce3eb7a2-bb5b-4da9-9748-79d1fc4f01cc).html

Abstract

The unimolecular dissociation reaction of vinyl bromide was investigated using the high-resolution pulsed field ionization-photoelectron (PFI-PE)-photoion coincidence method. The value of the 0 K dissociation energy (D₀) for the the C₂H₃^--Br bond was determined from the value of appearance energy for C₂H₃^- (vinyl radical) and the ionization energy (IE) for vinyl bromide. The high-level ab initio calculations for the IE of vinyl radical were performed, at the Gaussian-3 and the CSD(T,full)/CBS level of theory. The TPE spectrum of vinyl bromide were recorded in the energy range of 9.80-12.20 eV.

Citation Format(s)

[ RIS ] [ BibTeX ]

A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide. / Qian, X. M.; Lau, K. C.; Ng, C. Y.
In: Journal of Chemical Physics, Vol. 120, No. 23, 15.06.2004, p. 11031-11041.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Qian, XM, Lau, KC & Ng, CY 2004, 'A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide', Journal of Chemical Physics, vol. 120, no. 23, pp. 11031-11041. https://doi.org/10.1063/1.1739402

Qian, X. M., Lau, K. C., & Ng, C. Y. (2004). A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide. Journal of Chemical Physics, 120(23), 11031-11041. https://doi.org/10.1063/1.1739402

Qian XM, Lau KC, Ng CY. A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide. Journal of Chemical Physics. 2004 Jun 15;120(23):11031-11041. doi: 10.1063/1.1739402

Qian, X. M. ; Lau, K. C. ; Ng, C. Y. / A high-resolution pulsed field ionization-photoelectron-photoion coincidence study of vinyl bromide. In: Journal of Chemical Physics. 2004 ; Vol. 120, No. 23. pp. 11031-11041.