A dynamic model of the packed dehumidifier

Liquid desiccant dehumidification, a clean energy technique for creating comfortable environments has received a lot of interest. Several dynamic models have been proposed to predict the outlet air humidity ratio and temperature, however, a study on presenting variations of heat and mass transfer coefficients and thermal mass of desiccant during the dynamic dehumidification process was not encountered according to authors’ best knowledge. This gap is primarily due to the complex nature of the coupled heat and mass transfer processes, which make it challenging to capture the evolution of heat and mass transfer coefficients over time. In this study, variations of these parameters are analyzed at first. A theoretical study is conducted to show the thermal mass of the desiccant can be considered constant when changing the inlet air humidity ratio or desiccant temperature, simplifying the dynamic modeling process. While the variation of heat and mass transfer coefficients show significant impact in such conditions. Subsequently, a new method based on mass conservation is provided to determine the thermal mass of desiccant. By examining the cause-and-effect relationships between heat and mass transfer coefficients and outlet air humidity ratio, the evolution of heat and mass transfer coefficients following exponential laws is deduced by inversion. Then a dynamic model of packed dehumidifiers can be completed easily based on above derivations, and its viability is confirmed by experimental results. Compared to the existing method, the prediction accuracy can improve by 50% based on the proposed methods. This study characterizes evolution rules of heat and mass transfer coefficients over time, and with this, evolutions of outlet air parameters during the dynamic dehumidification process can be acquired conveniently based on the existing steady dehumidification model. © 2023 Elsevier Ltd.