A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center

Chun-Yuen Wong; Glenna So Ming Tong; Chi-Ming Che; Nianyong Zhu

doi:10.1002/anie.200600139

Author(s)

Chun-Yuen Wong
Glenna So Ming Tong
Chi-Ming Che
Nianyong Zhu

Detail(s)

Original language	English
Pages (from-to)	2694-2698
Journal / Publication	Angewandte Chemie - International Edition
Volume	45
Issue number	17
Publication status	Published - 21 Apr 2006
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.200600139 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-33746211345&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(b3269fc6-520a-487f-9c6e-08b3cf839bc8).html

Abstract

Making the band: A bis(pyridyl)allenylidene-ruthenium complex acts as a metalloligand for the binding of metal ions. The dinuclear complex [(16-TMC)ClRu=C=C=C(2-py)₂Ru(acac)₂]⁺ (16-TMC = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) features an intense low-energy metal-to-ligand charge transfer in an excited state delocalized over both Ru ions and the allenylidene bridge (see plot of the LUMO). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Research Area(s)

Cyclic voltammetry, Density functional calculations, pi interactions, Ruthenium, UV/Vis spectroscopy

Citation Format(s)

[ RIS ] [ BibTeX ]

A bis(pyridyl)allenylidene complex of ruthenium : A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center. / Wong, Chun-Yuen; Tong, Glenna So Ming; Che, Chi-Ming et al.

In: Angewandte Chemie - International Edition, Vol. 45, No. 17, 21.04.2006, p. 2694-2698.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Wong, C-Y, Tong, GSM, Che, C-M & Zhu, N 2006, 'A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center', Angewandte Chemie - International Edition, vol. 45, no. 17, pp. 2694-2698. https://doi.org/10.1002/anie.200600139

Wong, C-Y., Tong, G. S. M., Che, C-M., & Zhu, N. (2006). A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center. Angewandte Chemie - International Edition, 45(17), 2694-2698. https://doi.org/10.1002/anie.200600139

Wong C-Y, Tong GSM, Che C-M, Zhu N. A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center. Angewandte Chemie - International Edition. 2006 Apr 21;45(17):2694-2698. doi: 10.1002/anie.200600139

Wong, Chun-Yuen ; Tong, Glenna So Ming ; Che, Chi-Ming et al. / A bis(pyridyl)allenylidene complex of ruthenium : A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center. In: Angewandte Chemie - International Edition. 2006 ; Vol. 45, No. 17. pp. 2694-2698.

A bis(pyridyl)allenylidene complex of ruthenium : A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center