4f8-4f8 Ultraviolet absorption spectrum of Cs 2NaTbCl6

Hongli Wen; Peter A. Tanner

doi:10.1016/j.cplett.2011.04.024

4f⁸-4f⁸ Ultraviolet absorption spectrum of Cs ₂NaTbCl₆

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

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Author(s)

Hongli Wen
Peter A. Tanner

Detail(s)

Original language	English
Pages (from-to)	49-53
Journal / Publication	Chemical Physics Letters
Volume	508
Issue number	1-3
Publication status	Published - 18 May 2011

Link(s)

DOI	DOI https://doi.org/10.1016/j.cplett.2011.04.024 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-79955726380&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(299b22b7-b131-48d9-bbe6-3e1d9d299188).html

Abstract

The ultraviolet absorption spectrum of a crystal of Cs ₂NaTbCl₆ has been recorded at 15 and 35 K. Spectral features have been assigned to magnetic dipole zero phonon lines and TbCl63- moiety mode vibronic structure. A comparison is made of the derived electronic energy level scheme with that from two-photon excitation experiments and the agreement is good. The differences in spectral selection rules for these two approaches are highlighted. © 2011 Elsevier B.V. All rights reserved.