2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties

Wai-Fun Yeung; Tai-Chu Lau; Xin-Yi Wang; Song Gao; Lap Szeto; Wing-Tak Wong

doi:10.1021/ic060580m

Author(s)

Wai-Fun Yeung
Tai-Chu Lau
Xin-Yi Wang
Song Gao
Lap Szeto
And 1 others

Wing-Tak Wong

Detail(s)

Original language	English
Pages (from-to)	6756-6760
Journal / Publication	Inorganic Chemistry
Volume	45
Issue number	17
Publication status	Published - 21 Aug 2006

Link(s)

DOI	DOI https://doi.org/10.1021/ic060580m Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-33748699125&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(e0637818-9386-4aee-b1cb-6e51eca36001).html

Abstract

A series of cyano-bridged Ln^IIIRu^III₂ coordination polymers, Ph₄P{Ln(NO₃)₂[Ru(acac) ₂(CN)₂]₂} [Ln = Tb (1), Dy (2), Er (3), Gd (4); Hacac = acetylacetone] have been synthesized by the reaction of Ln(NO ₃)₃ with trans-Ph₄P[Ru-(acac) ₂(CN)₂] in methanol. X-ray crystallographic determination reveals that these compounds are isostructural and have a wavy (4,4) layer structure with the Ln³⁺ ions bridged by trans-[Ru(acac) ₂(CN)₂]^-. Magnetic studies shows that the magnetic coupling between the Ln(III) and Ru(III) ions through the cyano bridges in 1-4 is negligibly weak. © 2006 American Chemical Society.

Citation Format(s)

[ RIS ] [ BibTeX ]

2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties. / Yeung, Wai-Fun; Lau, Tai-Chu; Wang, Xin-Yi et al.

In: Inorganic Chemistry, Vol. 45, No. 17, 21.08.2006, p. 6756-6760.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Yeung, W-F, Lau, T-C, Wang, X-Y, Gao, S, Szeto, L & Wong, W-T 2006, '2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties', Inorganic Chemistry, vol. 45, no. 17, pp. 6756-6760. https://doi.org/10.1021/ic060580m

Yeung, W-F., Lau, T-C., Wang, X-Y., Gao, S., Szeto, L., & Wong, W-T. (2006). 2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties. Inorganic Chemistry, 45(17), 6756-6760. https://doi.org/10.1021/ic060580m

Yeung W-F, Lau T-C, Wang X-Y, Gao S, Szeto L, Wong W-T. 2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties. Inorganic Chemistry. 2006 Aug 21;45(17):6756-6760. doi: 10.1021/ic060580m

Yeung, Wai-Fun ; Lau, Tai-Chu ; Wang, Xin-Yi et al. / 2D LnIIIRuIII2 compounds constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, structures, and magnetic properties. In: Inorganic Chemistry. 2006 ; Vol. 45, No. 17. pp. 6756-6760.