低成本固相法合成 Na–β"-Al2O3 固体电解质陶瓷

null 王竹梅; null 张天峰; Hongwei 左洪威; null 谢志翔; null 李月明; null 程亮

doi:10.14062/j.issn.0454-5648.2018.09.06

低成本固相法合成 Na–β"-Al₂O₃ 固体电解质陶瓷

Translated title of the contribution: Synthesis of Na-βʺ-Al₂O₃ Solid Electrolytes by Solid-state Reaction Method

王竹梅^*, 张天峰, 左洪威, 谢志翔, 李月明, 程亮

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

1 Citation (Scopus)

Abstract

The Na-β"-Al₂O₃ solid electrolyte ceramic material was synthesized by a conventional solid-state reaction method with inexpensive industrial alumina as a raw material. The samples were characterized by X-ray diffraction and scanning electron microscopy, and the conductivity of the sample was tested by AC impedance method. The results indicate that the relative content of β"-Al₂O₃ phase is closely related to the Na content in Na_1.67(1+x)Li_0.33Al_10.67O₁₇ and the synthesis temperature when x=0.15, and the sintering temperature is 1 580℃. The maximum relative content of β"-Al₂O₃ phase is 97.19%. In this case, the microstructure of ceramics is relatively compact, its conductivity is 0.028 S/cm at 300℃ and the conductance activation energy is 0.259 eV.

Translated title of the contribution	Synthesis of Na-βʺ-Al₂O₃ Solid Electrolytes by Solid-state Reaction Method
Original language	Chinese (Simplified)
Pages (from-to)	1217-1221
Journal	硅酸盐学报 / Journal of the Chinese Ceramic Society
Volume	46
Issue number	9
DOIs	https://doi.org/10.14062/j.issn.0454-5648.2018.09.06
Publication status	Published - Sept 2018

Research Keywords

固体电解质
钠–β"-氧化铝固体电解质
离子电导率
低成本
sodium-beta"-alumina solid electrolyte
ionic conductivity
Sodium-beta"-alumina solid electrolyte
low cost

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@article{abcafe13b2f441f5baa32b68363028ea,

title = "低成本固相法合成 Na–β{"}-Al2O3 固体电解质陶瓷",

abstract = "以工业氧化铝为原料, 采用低成本埋烧工艺, 用传统固相法制备 Na–β{"}-Al2O3 相相对含量高的固体电解质陶瓷材料。采用综合热分析仪、X 射线衍射以及扫描电子显微镜对样品进行表征, 采用交流阻抗法测试了样品的电导率。结果表明: β{"}-Al2O3 相的相对含量与配方 Na1.67（1+x）Li0.33Al10.67O17 中的 Na 含量和合成温度密切相关, 陶瓷在 x=0.15、烧结温度为 1 580℃ 时, β{"}-Al2O3 相的相对含量最高, 达 97.19%, 此时陶瓷的微观结构较致密, 300℃ 的电导率为 0.028 S/cm、电导活化能为 0.259 eV。该方法制备工艺简单、适合工业大规模生产。",

keywords = "固体电解质, 钠–β{"}-氧化铝固体电解质, 离子电导率, 低成本, sodium-beta{"}-alumina solid electrolyte, ionic conductivity, Sodium-beta{"}-alumina solid electrolyte, low cost, 固體電解質, 鈉–β{"}-氧化鋁固體電解質, 離子電導率, 低成本, 固体电解质, 钠–β{"}-氧化铝固体电解质, 离子电导率, 低成本",

author = "王竹梅 and 张天峰 and 左洪威 and 谢志翔 and 李月明 and 程亮",

year = "2018",

month = sep,

doi = "10.14062/j.issn.0454-5648.2018.09.06",

language = "繁体中文",

volume = "46",

pages = "1217--1221",

journal = "硅酸盐学报 / Journal of the Chinese Ceramic Society",

issn = "0454-5648",

publisher = "Chinese Ceramic Society",

number = "9",

}

TY - JOUR

T1 - 低成本固相法合成 Na–β"-Al2O3 固体电解质陶瓷

AU - 王竹梅, null

AU - 张天峰, null

AU - 左洪威, null

AU - 谢志翔, null

AU - 李月明, null

AU - 程亮, null

PY - 2018/9

Y1 - 2018/9

N2 - 以工业氧化铝为原料, 采用低成本埋烧工艺, 用传统固相法制备 Na–β"-Al2O3 相相对含量高的固体电解质陶瓷材料。采用综合热分析仪、X 射线衍射以及扫描电子显微镜对样品进行表征, 采用交流阻抗法测试了样品的电导率。结果表明: β"-Al2O3 相的相对含量与配方 Na1.67（1+x）Li0.33Al10.67O17 中的 Na 含量和合成温度密切相关, 陶瓷在 x=0.15、烧结温度为 1 580℃ 时, β"-Al2O3 相的相对含量最高, 达 97.19%, 此时陶瓷的微观结构较致密, 300℃ 的电导率为 0.028 S/cm、电导活化能为 0.259 eV。该方法制备工艺简单、适合工业大规模生产。

AB - 以工业氧化铝为原料, 采用低成本埋烧工艺, 用传统固相法制备 Na–β"-Al2O3 相相对含量高的固体电解质陶瓷材料。采用综合热分析仪、X 射线衍射以及扫描电子显微镜对样品进行表征, 采用交流阻抗法测试了样品的电导率。结果表明: β"-Al2O3 相的相对含量与配方 Na1.67（1+x）Li0.33Al10.67O17 中的 Na 含量和合成温度密切相关, 陶瓷在 x=0.15、烧结温度为 1 580℃ 时, β"-Al2O3 相的相对含量最高, 达 97.19%, 此时陶瓷的微观结构较致密, 300℃ 的电导率为 0.028 S/cm、电导活化能为 0.259 eV。该方法制备工艺简单、适合工业大规模生产。

KW - 固体电解质

KW - 钠–β"-氧化铝固体电解质

KW - 离子电导率

KW - 低成本

KW - sodium-beta"-alumina solid electrolyte

KW - ionic conductivity

KW - Sodium-beta"-alumina solid electrolyte

KW - low cost

KW - 固體電解質

KW - 鈉–β"-氧化鋁固體電解質

KW - 離子電導率

KW - 低成本

KW - 固体电解质

KW - 钠–β"-氧化铝固体电解质

KW - 离子电导率

KW - 低成本

UR - http://www.scopus.com/inward/record.url?scp=85056536119&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85056536119&origin=recordpage

U2 - 10.14062/j.issn.0454-5648.2018.09.06

DO - 10.14062/j.issn.0454-5648.2018.09.06

M3 - RGC 21 - Publication in refereed journal

SN - 0454-5648

VL - 46

SP - 1217

EP - 1221

JO - 硅酸盐学报 / Journal of the Chinese Ceramic Society

JF - 硅酸盐学报 / Journal of the Chinese Ceramic Society

IS - 9

ER -

低成本固相法合成 Na–β"-Al₂O₃ 固体电解质陶瓷

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