Efficient bifunctional catalyst enables high-performance zinc-nitrate / ethanol batteries for sustainable energy storage

Description

Zinc-nitrate batteries are a primary non-rechargeable energy storage system that utilizes the redox potential difference between zinc and nitrate ions to store and release electrical energy. A research team co-led by chemists from City University of Hong Kong (CityU) have developed a high-performance rechargeable zinc-nitrate/ethanol battery by introducing an innovative catalyst. They successfully designed and synthesized an efficient tetraphenylporphyrin (tpp) modified heterophase rhodium-copper alloy metallene (RhCu M-tpp). This bifunctional catalyst exhibits remarkable capabilities in both the electrocatalytic nitrate reduction reaction (NO3RR) and ethanol oxidation reaction (EOR) in a neutral medium, overcoming the monofunctional limitations of traditional metal-based solid catalysts and providing a valuable reference for the design of sustainable energy storage in the future.